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Progress in Chemistry 2020, Vol. 32 Issue (10): 1582-1591 DOI: 10.7536/PC200211 Previous Articles   Next Articles

Preparation and Pseudocapacitor Properties of Self-Supported Nickel Sulfides Electrode Materials

Shaofei Zhao1, Peng Liu1, Gao Cheng1, Lin Yu1,**(), Huaqiang Zeng1,2,**()   

  1. 1. School of Chemical Engineering & Light Industry, Guangdong University of Technology, Guangzhou 510006, China
    2. Nanobio laboratory, Singapore 138669, Singapore
  • Received: Revised: Online: Published:
  • Contact: Lin Yu, Huaqiang Zeng
  • About author:
    **e-mail:(Lin Yu)
    (Huaqiang Zeng)
  • Supported by:
    National Natural Science Foundation of China(No.21306026); National Natural Science Foundation of China(21576054); National Natural Science Foundation of China(51678160)
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With the advantages of ultra-high power density, and super specific capacitance, nickel sulfides pseudocapacitors have been supposed as one of the ideal devices for energy storage. However, the application of those pseudocapacitors have been subjected to the poor cycle stability and low conductivity. Up to now, extensive efforts have been made to increase the conductivity and cycle stability. Among which, the self-supported electrode materials have been regarded as a effective solution to reduce internal resistance for high rate capacitance. This paper reviews the main methods to prepare self-supported nickel sulfides pseudocapacitor electrode materials, and summarize the relationship between morphology and capacitance property, which focus on the modification of conductive substrates, the compositing with graphene or others elements, the design of flexible materials, etc. Finally, the research directions of these materials are further proposed.

Contents

1 Introduction

2 Preparation of nickel sulfides materials

2.1 Solvothermal method

2.2 Electrodeposition method

2.3 Other preparation methods

3 Structural optimization of nickel sulfides materials

3.1 Modification of current collector

3.2 Doping with other ions

3.3 Preparation of composite materials

3.4 Design of flexible electrode

4 Conclusion and outlook

Key words: supercapacitor, pseudocapacitor, nickel sulfides, specific capacitance, cycle property
Fig.1 Schematic of different types of redox mechanisms of pseudocapacitances[16]
Fig.2 SEM micrographs of Ni3S2 with net structure prepared by one pot hydrothermal method[14, 22]
Fig.3 SEM images of the Ni3S2 films developed at different temperatures of (a) 140 ℃, (b) 160 ℃, and (c) 180 ℃. (d) Side view image of the NS-160 film on Ni foam[33]
Fig.4 Schematic diagram for preparation of Ni3S2 thin film with different pore size, and the contact relation between electrolyte ions and pores with different sizes in the electrochemical reaction process[35]
Fig.5 Characterization results of the urchin-like Ni3S2 grown on the Ni foam substrate (Ni3S2@Ni): scanning electron microscopy (SEM) images (A~D) at different magnifications[29]
Fig.6 SEM images with different magnifications for (a~c) G2, (d~f) G0, (g~i) G1[39]
Fig.7 Illustration of the two-step approach to prepare Ni3S2 nanosheets[41]
Fig.8 SEM images of (a,b) Ni(Cu) and the (c-e) Ni3S2/Ni 6 min electrode. Cross-sectional SEM images of (f) Ni(Cu), (g) Ni3S2/Ni 2 min electrode, and (h) Ni3S2/Ni 6 min electrode. (i) Schematic illustration of Ni3S2/Ni electrode preparation[42]
Fig.9 SEM images of the intermediates obtained at different time for Ni-Co precursor: (a) 480, (b) 540, (c) 600, and (d) 720 min; SEM images of Ni-Co precursor samples synthesized with different concentrations of NH4F: (e) 0, (f) 10, (g) 12, and (h) 15 mmol[65]
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