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Progress in Chemistry 2020, Vol. 32 Issue (7): 978-988 DOI: 10.7536/PC200201 Previous Articles   Next Articles

• Review •

Heterogeneous Fenton Catalytic Oxidation for Water Treatment

Lida Jia1, Qingrui Zhang1,2,**()   

  1. 1. Hebei Key Laboratory of Heavy Metal Deep-Remediation in Water and Resource Reuse and Key Laboratory of Applied Chemistry, Yanshan University, Qinhuangdao 066004, China
    2. State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, China
  • Received: Online: Published:
  • Contact: Qingrui Zhang
  • About author:
    * ** e-mail:
  • Supported by:
    National Natural Science Foundation of China(21876145); National Natural Science Foundation of China(51578476)
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Advanced oxidation technology(AOPs) is a hot issue in current water treatment research, such as the representative Heterogeneous Fenton catalytic oxidation. It can generate active oxygen species such as hydroxyl radicals(·OH) during the reaction, which attack organic pollutants unselectively and gradually decompose organic macromolecules into small molecules, achieving the efficient removing of toxic and harmful pollutants. Compared with homogeneous Fenton reactions, heterogeneous Fenton reactions have various advantages, such as wide pH response, recyclability of catalysts, and no generation of iron mud. However, considering their intrinsic characteristics and limits of solid-phase catalysts, there are still some problems inhibiting the large-scale application, such as low activity under neutral conditions, low utilization of hydrogen peroxide(H2O2), and low conversion rate of Fe(Ⅲ)/Fe(Ⅱ). This article summarizes the heterogeneous Fenton reaction mechanism involving different active oxygen species as well as various heterogeneous Fenton catalysts and their applications in control of organic pollutants and provides a reference for continuing research on heterogeneous Fenton catalysts.

Contents

1 Introduction

2 Classical Fenton and heterogeneous Fenton reaction

3 Mechanism of the heterogeneous Fenton reaction

3.1 Hydroxyl radical mechanism

3.2 Singlet oxygen mechanism

3.3 High-valent iron species mechanism

4 Development and utilization of heterogeneous Fenton co-catalyst

4.1 Accelerate interface electron migration

4.2 Increase active site

5 Heterogeneous Fenton catalytic oxidation for organic wastewater

5.1 Dye wastewater

5.2 Antibiotic wastewater

5.3 Phenolic wastewater

6 Conclusion and outlook

Key words: heterogeneous Fenton, mechanism, co-catalyst, organic wastewater
Fig.1 Mechanisms proposed up to now for the heterogeneous Fenton reaction
Fig.2 Proposed reaction mechanisms involved in the Fh-OA system under visible light irradiation[13]
Fig.3 Schematic diagram of molybdenum-assisted Fenton catalytic reaction[16]
Fig.4 Mechanistic presentation of possible reactions involved in the thermal Fenton reaction(with Simplified Notations Used for the Various Iron Complexes)[7]
Fig.5 Possible oxidative mechanism of CBZ in FePcF16-O-FePcF16/H2O2 system[21]
Fig.6 Schematic illustration for the possible hydroxyl radical generation mechanism in the α-FeOOH-HA/H2O2 system[24]
Fig.7 Organic pollutants degradation in Sed/AA/H2O2 system[30]
Fig.8 Scheme of the possible mechanism for Fe-N/pentlandite/Al2O3/C catalyst in the Fenton reaction[34]
Fig.9 Schematic illustration of the co-catalytic mechanism of MoS2 in AOPs[35]. Copyright 2018, Elsevier
Fig.10 Schematic of SAFe-SBA and AGFe-SBA catalyst synthesis[39]
Fig.11 The possible underlying mechanism of the process: activation
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