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Progress in Chemistry 2020, Vol. 32 Issue (7): 989-1002 DOI: 10.7536/PC191202 Previous Articles   Next Articles

• Review •

Imprinted Composite Membranes

Runtian Wang1,2, Chunli Liu1,2,**(), Zhenbin Chen1,2,**()   

  1. 1. College of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China
    2. State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China
  • Received: Online: Published:
  • Contact: Chunli Liu, Zhenbin Chen
  • About author:
    ** e-mail: (Chunli Liu);
    (Zhenbin Chen)
  • Supported by:
    joint fund between Shenyang National Laboratory for Materials Science and State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals(18LHZD003); joint fund between Shenyang National Laboratory for Materials Science and State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals(18LHPY004)
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Imprinted composite membranes(IcMs) not only possess the efficient separation performance of membranes, but also possess the selective separation performance of imprinted polymers, which have attracted extensive attention all over the world for their well and precise separation property for target substances and high membrane flux. However, the research progress on IcMs has not been summarized yet, and problems existed in research process and the future perspective of IcMs are not analyzed and forecast. This paper summarizes the research and development process of IcMs and the research progress in preparation technology of IcMs, then classify IcMs according to their structure to several categories, namely, IcMs of a single-layer structure, IcMs of a dual-layer structure, IcMs of a multi-layer structure, IcMs of 3D macroporous structure and IcMs with smart sensing and separation properties. Finally, the preparation methods, structural characteristics and identification/separation properties of IcMs, and the potential problems coupled with those aspects are summarized and a future developing direction of this field is prospected.

Contents

1 Introduction

2 Imprinted membranes

2.1 History of imprinted membranes

2.2 Recognition mechanism and transfer mechanism of imprinted composite membranes

3 Classification of imprinted composite membranes based on structural differences

3.1 Single-layer structure imprinted composite membranes

3.2 Dual-layer structure imprinted composite membranes

3.3 Multi-layer structure imprinted composite membranes

3.4 3D macroporous imprinted composite membranes

4 Smart imprinted composite membranes

4.1 Switch-smart imprinted composite membrane

4.2 Integrated-smart imprinted composite membrane

5 Conclusion and outlook

Key words: Imprinted composite membranes, structural design, preparation method, separation properties
Fig.1 The preparation route of imprinted separation layer and recognition mechanism
Fig.2 Mass transfer mechanism solution-diffusion model of imprinting membranes[31] Copyright 2001, Elsevier
Fig.3 “Gate”model[30] Copyright 1999, Elsevier
Fig.4 Schedule of diffusion of template imprinting composite membrane[34]
Fig.5 Schematic illustration of constructing IcMs for Cloxicillin[39]. Copyright 2018, Elsevier
Fig.6 Schematic illustration of constructing IcMs for D-Tryptophan[10].Copyright 2017, Elsevier
Fig.7 Schematic illustration of constructing IcMs for Cu2+[13]. Copyright 2018, Elsevier
Fig.8 Schematic illustration of constructing IcMs for artemisinin[46]. Copyright 2014, Elsevier
Fig.9 Schematic illustration of constructing IcMs for ibuprofen[47]. Copyright 2018, Elsevier
Fig.10 Schematic illustration of constructing IcMs for enrofloxacin[48]. Copyright 2019, Elsevier
Fig.11 Schematic illustration of constructing IcMs for artemisinin[51]. Copyright 2016, Wiley
Fig.12 Schematic illustration of constructing IcMs for Mo(Ⅵ)[52].Copyright 2016, Elsevier
Fig.13 Schematic illustration of constructing IcMs for norfloxacin[53]. Copyright 2018, Elsevier
Fig.14 Schematic illustration of constructing IcMs for norfloxacin[54].Copyright 2017, Royal Society of Chemistry
Fig.15 Schematic illustration of constructing IcMs for ibuprofen[55].Copyright 2018, Elsevier
Fig.16 Schematic illustration of constructing IcMs for enoxacin[56].Copyright 2019, Elsevier
Fig.17 Schematic illustration of constructing IcMs for artemisinin[57]. Copyright 2015, Elsevier
Fig.18 Schematic illustration of constructing IcMs for Li+[58]. Copyright 2018, Elsevier
Fig.19 Schematic illustration of constructing IcMs for ovalbumin[59]. Copyright 2015, Wiley
Fig.20 Schematic illustration of the synthesis of IcMs for artemisinin[60]. Copyright 2019, America Chemistry Society
Fig.21 Schematic illustration of the sythesis of IcMs for Li+[61]. Copyright 2019, Elsevier
Fig.22 Scheme for the preparation of IcMs for Pd2+[62]. Copyright 2020, Elsevier
Fig.23 Scheme for the preparation of IcMs for emodin[63]. Copyright 2019, Elsevier
Fig.24 Scheme for the preparation of IcMs for Dy3+[64]. Copyright 2017, Elsevier
Fig.25 Scheme for the preparation of IcMs for ciprofloxacin[23]. Copyright 2017, Elsevier
Fig.26 Scheme for the preparation of IcMs for Eu3+[66]. Copyright 2018, Elsevier
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Abstract

Imprinted Composite Membranes