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Progress in Chemistry 2020, Vol. 32 Issue (6): 727-737 DOI: 10.7536/PC191108 Previous Articles   Next Articles

• Review •

Synthesis of Polyethylene and Polyhalogenated Olefin by Controlled/“Living” Radical Polymerization

Lianwei Sun1, Zhonghe Sun2,**(), Xue Wang3, Lin Xu3, Anchao Feng1,4,**(), Liqun Zhang1,4   

  1. 1. Beijing Key Laboratory of Preparation and Processing of New Polymer Materials, Beijing University of Chemical Technology, Beijing 100029, China
    2. School of Chemistry, Beihang University, Beijing 100191, China
    3. SINOPEC Beijing Research Institute of Chemical Industry, National Engineering Research Center for Synthesis of Novel Rubber and Plastic Materials, Beijing 102500, China
    4. School of Materials Science and Engineering, Center of Advanced Elastomer Materials, Beijing University of Chemical Technology, Beijing 100029, China
  • Received: Revised: Online: Published:
  • Contact: Zhonghe Sun, Anchao Feng
  • Supported by:
    the National Natural Science Foundation of China(21704001); SINOPEC(H2019485); the Beijing Advanced Innovation Center for Soft Matter Science and Engineering.()
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Controlled/“living” radical polymerization(CLRP) can be used to synthesize polymers with narrow molecular weight distribution and few chain defects(such as Polyethylene(PE), polyvinyl chloride(PVC), polyvinylidene chloride(PVDC) and polyvinylidene fluoride(PVDF)), and it is easy to copolymerize the above monomer with other monomers to obtain block polymers. In this paper, we investigate the preparation of polyethylene and polyhalogenated olefin polymers by controlled/"living" radical polymerization, (for example, iodine transfer polymerization(ITP), nitroxide-mediated living radical polymerization(NMP), reversible addition fragmentation chain transfer(RAFT) polymerization and organometallic mediated radical polymerization(OMRP)) and point out the development trend.

Contents

1 Introduction
2 Preparation of polyethylene by Controlled/“living” radical polymerization.

2.1 RAFT method

2.2 OMRP method

3 Controlled/“living” radical polymerization of polyvinyl chloride

3.1 NMP method

3.2 OMRP method

3.3 RAFT method

4 Preparation of polyvinylidene chloride by controlled/“living” radical polymerization

4.1 ITP method

4.2 RAFT method

5 Preparation of polyvinylidene fluoride by controlled/“living” radical polymerization.

5.1 ITP method

5.2 RAFT method

5.3 OMRP method

6 Conclusion and outlook
Key words: controlled/“living” radical polymerization;, polyethylene, polyhalogenated olefins
Fig. 1 Preparation of PVC by NMP[48]
Fig. 2 The mechanism of SET-DTLRP living polymerization of VC monomer[53]
Fig. 3 RAFT polymerization process of VC monomer and migration characteristics as macromolecular plasticizer[68]
Fig. 4 Synthesis pathways of PVDC and PEO copolymers prepared by RAFT method[82]
Fig. 5 Synthesis pathways of PVDC and PEO copolymers prepared by RAFT method[84]
Fig. 6 Synthesis pathways of PVDC-b-PS by IP method[100]
Fig. 7 Pathway to synthesize PVDF-b-PDMAEMA with the joint use of RAFT and ATRP[103]
Fig. 8 Synthesis pathways of PVDF-b-PVDF by RAFT[105]
Fig. 9 The mechanism of polymerization of VDF monomer catalyzed by Mn2(CO)10[106]
Table 1 Structure of suitable monomers and corresponding RAFT agents for RAFT polymerization
Monomers Structure of RAFT agents ref Monomers Structure of RAFT agents ref
vinylidene chloride 65, 67
ethylene 35
65, 67
36
65, 67
78, 79
36
84, 80
81, 83
84, 85
38
vinylidene fluoride 101, 102
vinyl chloride 48
103
65, 67
104
105
68
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