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Progress in Chemistry 2020, Vol. 32 Issue (6): 738-751 DOI: 10.7536/PC190930 Previous Articles   Next Articles

• Review •

Compatibilization Strategies of PLA-Based Biodegradable Materials

Yue Ding1,2,*(), Bo Lu2, Junhui Ji2,**()   

  1. 1. School of Material and Chemical Engineering, Xuzhou University of Technology, Xuzhou 221111, China
    2. National Engineering Research Center of Engineering Plastics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • Received: Revised: Online: Published:
  • Contact: Yue Ding, Junhui Ji
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With the energy crisis and environmental pollution, biodegradable polymers have attracted considerable interest because these compounds are environmentally friendly and renewable. Poly(lactic acid)(PLA) is considered as one of the most promising biodegradable polymers because of its excellent biocompatibility, biodegradability, easy processability and high strength. However, its poor ductility and impact properties seriously restrict the application. Polymer blending is an economical and effective way to solve the shortcomings. Unfortunately, PLA is thermodynamically immiscible with most polymers. It has been established that the compatibilization is a famous strategy to improve the miscibility of the blends by enhancing the adhesion between the phases. Thus, recent studies focus on various compatibilizers to obtain excellent performance of PLA-based blends. This review summarizes the recent development in compatibilization strategies applied to PLA-based blends.

Contents

1 Introduction
2 Study on Compatibility of Biodegradable Materials

2.1 Compatibilization mechanism

2.2 Compatibilization of copolymers

2.3 Compatibilization of reactive polymers

2.4 Compatibilization of low molecular weight components

2.5 Dynamic vulcanization and interfacial compatibilization

2.6 Compatibilization of nanoparticles

3 Conclusion and outlook
Key words: poly(lactic acid), blend, compatibilization, interfacial interaction, miscibility
Fig. 1 Compatibilization methods and compatibilizers of PLA polymer blends[25, 26]
Fig. 2 Morphology and particle size change of PLA/PBS compatibilized by rPBSL[27]
Fig. 3 SEM images of PCC/PMMA with PVAC:(a) 0%,(b) 2.5%,(c) 5%,(d) 10%[32]
Fig. 4 Stretching diagrams of PLA/PBAT with PLA-PEG-PLA compatibilizers[41]
Fig. 5 Reactions between the functional groups of reactive compatibilizer and terminal groups of polymers[56]
Fig. 6 Stretching diagrams of PLLA/PVDF with Janus compatibilizers[74]
Fig. 7 The chemical reaction diagram in PLA/MGST blends compatibilized by ESO[97]
Fig. 8 SEM images of the dynamically vulcanized blend samples after being etched in dichloromethane and Digital photographs of swelling experiments[115]
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