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Progress in Chemistry 2019, Vol. 31 Issue (11): 1615-1622 DOI: 10.7536/PC190808 Previous Articles   

External Field Enhanced Environmental Responsive Solid Extraction Technology

Liangrong Yang1,3, Huifang Xing1,3, Hongnan Qu1,3, Jiemiao Yu1,3, Huizhou Liu1,2,3,**()   

  1. 1. Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
    2. National Science Library, Chinese Academy of Sciences, Beijing 100190, China
    3. College of Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
  • Received: Online: Published:
  • Contact: Huizhou Liu
  • About author:
    ** E-mail:
  • Supported by:
    National Natural Science Foundation of China(21922814); National Natural Science Foundation of China(21676273); National Natural Science Foundation of China(U1507203); National Natural Science Foundation of China(31961133019); National Natural Science Foundation of China(21921005); Chinese Academy of Sciences Youth Innovation Promotion Talent Project(2016043); Beijing Natural Science Foundation Project(2194086)
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Efficient, precise and controllable separation of target compounds in low concentration and large volume complex solutions is a world frontier in the field of chemical separation science. Solid phase extraction technology currently faces two challenges in industrial separation of low-concentration complex systems. On the one hand, it is difficult to give consideration to both of the high selective precision capture and the mild green desorption. On the other hand, solid phase extraction technology lacks efficient separation process and equipment for large scaled continuous separation. This review summarizes the research progress of new environmental responsive solid phase extraction technology, magnetic field responsive solid phase extraction technology, electric field- and ultrasound field- assisted solid phase extraction technology in order to solve the problems of current solid phase extraction technology, and achieve the efficient and precise separation for low concentration complex systems. Finally, the research and development direction of solid phase extraction technology in this application field is prospected. In this review, the key scientific issues of external field enhanced environmental responsive solid phase extraction technology, including environmental responsive problems, controllable separation problems and process amplification problems, are further discussed. Besides, measures and suggestions are proposed for the development of related fields.

Key words: external field enhancement, environmental responsive, solid phase extraction, magnetic separation, extraction separation
Fig. 1 Schematic diagram of solid phase extraction
Fig. 2 The challenges of solid phase extraction applied in complex industrial separation systems with low concentrations
Fig. 3 Schematic diagram of novel environmental responsive solid phase extraction technology and magnetic field responsive solid phase extraction technology
Fig. 4 Two-dimensional infrared synchronization correlation spectrum(a) and asynchronous correlation spectrum(b)[12]
Fig. 5 Temperature /pH responsive magnetic nanoparticle and interface regulated aggregation and depolymerization behavior[14]
Fig. 6 Temperature responsive aptamer solid phase extraction adsorbent and interface regulated separation of thrombin
Fig. 7 Light responsive aptamer solid phase extraction adsorbent and interface regulated separation of thrombin
Fig. 8 The comparation between novel solid phase extraction technology and the traditional method
Fig. 9 Magnetic responsive solid phase extraction technology
Fig. 10 Analysis of reasons for slow adsorption rate
Table 1 Comparison of domestic and foreign counterparts
Adsorbent qm
(mg/g)		 E. T.
(min)		 pH range Ref
γ-Fe2O3@δ-FeOOH 25.8 — 2.5 25
Fe3O4@PAA-DETA 11.24 — 5.0 26
NiFe2O4 30 — 5.0 27
Fe3O4-PEI-MMT 8.8 — 5.0 28
Fe3O4-Cyanex-301 30.8 120 2.0 29
ZnFe2O4-Ce3+ 57.24 4320 2.0 30
Poly(MMA-DVB-GMA)-EDA 61.35 60 2.0~3.0 31
Fe3O4@polypyrrole 169.49 180 1.0~6.0 32
Poly(GMA-EGDMA)-PEI 137.7 120 1.0~6.0 33
Poly(MA-DVB)-EDA ~36 60 3.0 34
Magnetic chitosan beads 69.4 > 60 3.0~5.0 19b
Magnetic chitosan-EDA 51.813 10 2.0 35
Magnetic chitosan-CAGS 58.48 110 2.0 19c
Chitosan/ montmorillonite 35.71 100 1.0~3.0 36
Magnetic chitosan nanoparticles 55.80 150 2.0~3.0 37
Cyclodextrin-chitosan/GO 67.66 — 1.0~3.0 38
MnFe2O4/Chitosan 15.4 360 6.0 39
MnFe2O4-Chitosan 51.79 480 5.0 39
Fe3O4-Fungus@alginate-PAA 6.97 720 1.0 40
Fe3O4@PVA-PEI 88.4 8 1.0~3.0 41
Fe3O4@PGMA-PEI 492.6 10 1.0~7.0 42
Fe3O4@Pst-MIMCl 104.0 30 1.0~7.0 43
Fe3O4@SiO2@CE-EDA 171.5 10 1.0~6.0 44
Fe3O4@SiO2@CTS-PEI 236.4 60~120 1.0~6.0 45
Fe3O4@SiO2@CTS-GTMAC 233.1 40~120 1.0~7.0 43
Fig. 11 Difficulties in continuous amplification of magnetic separation devices
Fig. 12 Novel gas-assisted superparamagnetic continuous extraction technology and equipment
Fig. 13 Gas-assisted magnetic separation used for continuous separation and purification of protein[46]
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