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Progress in Chemistry 2020, Vol. 32 Issue (4): 417-422 DOI: 10.7536/PC190713 Previous Articles   Next Articles

Carbon Dioxide Smart Materials Based on Chitosan

Jing Wen, Yuhong Li, Li Wang, Xiunan Chen, Qi Cao, Naipu He*()   

  1. School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China
  • Received: Revised: Online: Published:
  • Contact: Naipu He
  • Supported by:
    the National Natural Science Foundation of China(21164003)
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It is a main strategy that carbon dioxide (CO2) in the atmosphere is effective utilized, and its concentration is balanced by capture and conversion of CO2. Generally, CO2 responsive polymers are prepared by alkene monomers containing amine groups. Their response and capture properties for CO2 are improved by grafting polymerization or combining with other functional molecules. Natural polymers including polysaccharide and protein are considered as excellent candidates to prepare environmentally friendly polymers because of their rich resources, non-toxicity, biodegradability and good biocompatibility. Additional, chitosan contains a large number of amino groups, so it is employed to prepare CO2 smart materials and exhibits specific advantages. In the current paper, firstly, CO2 responsive polymer and chitosan(CS) are introduced. Secondly, advance in CO2 responsive polymers and capture materials based on chitosan is reviewed. Finally, a prospect for smart materials based on chitosan in the future is provided.

Contents

1 Introduction

2 Carbon dioxide responsive polymers

3 Chitosan

4 Carbon dioxide responsive polymers based on chitosan

5 Capture materials based on chitosan for carbon dioxide

6 Conclusion and outlook

Key words: chitosan, responsive polymers, carbon dioxide capture, smart materials
Fig. 1 CO2-switchable functional groupsin turn: tertiary amine, amidine, guanidine, imidazole, and carboxylic acid
Fig. 2 Reaction of amidines and amines with CO2 and water to form bicarbonate salts[9]
Fig. 3 Reversible response mechanism of carboxylic acid to CO2 gas molecule
Fig. 4 Reversible covalent binding mechanism of primary amine to CO2 gas molecule
Fig. 5 Preparation of chitosan by deacetylation of chitin
Fig. 6 Synthesis of CS-g-DMAEMA[27]
Fig. 7 Transition of CS-g-DMAEMA between protonated and deprotonated states by CO2/N2 [27]
Fig. 8 The CO2-switchability of the CNC hydrogel[29]
Fig. 9 Schematic illustration of the preparation of CNF-g-PDMAEMA aerogel for switchable oil-water separation[30]
Fig. 10 Schematic illustration of reversible CO2 capture by humidity swing[40]
Fig. 11 Microcosmic state and adsorption properties of chitosan-SiO2 nanoparticles[43]
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