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Progress in Chemistry 2020, Vol. 32 Issue (2/3): 249-261 DOI: 10.7536/PC190616 Previous Articles   Next Articles

Synthesis and Applications of Dendrimer-Based Inorganic Nanoparticles

Tianyou Chen1,2, Zihao Wang2, Zizheng Xu2, Zushun Xu2, Zheng Cao1,**()   

  1. 1. Jiangsu Key Laboratory of Environmentally Friendly Polymeric Materials, School of Materials Science and Engineering, Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering, Changzhou University, Changzhou 213164, China
    2. Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei Key Laboratory of Polymer Materials, School of Materials Science and Engineering, Hubei University, Wuhan 430062, China
  • Received: Online: Published:
  • Contact: Zheng Cao
  • About author:
    ** e-mail:
  • Supported by:
    National Natural Science Foundation of China(21802035); National Natural Science Foundation of China(21704008); National Natural Science Foundation of China(51573039); Jiangsu Key Laboratory of Environmentally Friendly Polymeric Materials, and the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)()
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Dendrimer has several unique properties, including well-defined and highly branched three-dimension structures, uniform size, internal space, substantial number of surface groups, and so forth. Thus, dendrimer has potential applications in catalysis, sensing, and biomedical applications. To improve or achieve these applications, inorganic nanoparticles are incorporated to generate dendrimer-based inorganic nanoparticles. On the other hand, the presence of dendrimers can inhibit the aggregation and improve the stability of inorganic nanoparticles in solution, preserving the excellent properties of these nanoparticles. Over the past decades, dendrimer-based inorganic nanoparticles have attracted wide attention of many researchers owing to their excellent properties and potential applications. Based on the distinct structures, dendrimer-based inorganic nanoparticles have three categories:(1) dendrimer-encapsulated inorganic nanoparticles;(2) dendrimer-stabilized inorganic nanoparticles;(3) dendron-stabilized inorganic nanoparticles. Here we review the advances of the synthesis and applications of dendrimer-based inorganic nanoparticles mainly in recent five years, focusing on catalysis, sensing and biomedical applications. And we outlook the future development of dendrimer-based inorganic nanoparticles.

Key words: dendrimer, inorganic nanoparticle, synthesis, application
Fig.1 Schematic structures of (A) dendrimer-encapsulated inorganic nanoparticles,(B) dendrimer-stabilized inorganic nanoparticles,(C) dendron-stabilized inorganic nanoparticles
Fig.2 Synthesis of dendrimer-encapsulated inorganic nanoparticles[13]
Fig.3 Schematic illustration of the synthesis of dendrimer-encapsulated Pt nanoparticles with large sizes[47]. The schematic structures of (A) a PAMAM dendrimer,(B) a PAMAM dendrimer terminated with alkyl chains, and (C) a dendrimer-encapsulated Pt nanoparticle with a large size
Fig.4 Synthesis of conjugated thiophene dendron-stabilized gold nanoparticle[61]
Fig.5 Dendrimer-encapsulated copper nanoparticles as a chemoselective and regenerable hydrogenation catalyst[29]
Scheme 1 Oxidation of flavonol
Scheme 2 (A) Sonogashira coupling of iodobenzene and phenylacetylene,(B) Suzuki-miyaura cross-coupling
Fig.6 Lactonization over dendrimer-encapsulated Au nanoparticles[129]
Scheme 3 Azide alkyne cycloaddition of benzyl azide and phenylacetylene
Fig.7 Schematic illustration of the synthesis of folic acid-modified, dendrimer-stabilized gold nanoparticle[55]
Fig.8 Synthesis route of dendrimer-encapsulated gold nanoparticles used as carriers of thiolated anticancer drugs[149]
Fig.9 Schematic illustration of dendrimer-encapsulated nanoparticle for photothermal therapy[153]
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