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Progress in Chemistry 2020, Vol. 32 Issue (1): 93-102 DOI: 10.7536/PC190607 Previous Articles   Next Articles

Special Issue: 电化学有机合成

Synthesis of Bottlebrush Polymers by Ring-Opening Metathesis Polymerization

Kerui Chen1, Xin Hu2,**(), Jiangkai Qiu1,**(), Ning Zhu1,**(), Kai Guo1   

  1. 1. College of Biotechnology and Pharmaceutical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211800, China
    2. College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211800, China
  • Received: Online: Published:
  • Contact: Xin Hu, Jiangkai Qiu, Ning Zhu
  • About author:
    ** E-mail: (Xin Hu);
    (Jiangkai Qiu);
    (Ning Zhu)
  • Supported by:
    National Natural Science Foundation of China(21878145); Jiangsu Synergetic Innovation Center for Advanced Bio-Manufacture(XTD1823); Jiangsu Synergetic Innovation Center for Advanced Bio-Manufacture(XTB1802)
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Bottlebrush polymers are a class of comb polymers that have the unique side chain structures and properties. Functional bottlebrush polymers have found broad applications in photonic crystals, surfactants, pharmaceutical carriers, antifouling coatings and smart materials. The synthetic strategies to bottlebrush polymers by ring-opening metathesis polymerization (ROMP) exhibit various advantages, such as simple synthesis steps, high polymer graft density and uniform side chain composition. Well control of polymer composition, molecular weight and molecular weight dispersity could be achieved by ROMP. This review summarizes the synthesis of homo, block, Janus, core-shell bottlebrush copolymers via ROMP. Moreover, the advances in finely controlling the bottlebrush polymer architecture are discussed.

Key words: bottlebrush polymers, ring-opening metathesis polymerization, copolymers
Fig. 1 Methods for synthesizing bottlebrush polymers[5]
Scheme. 1 Synthesis of bottlebrush homopolymers by anionic polymerization and ring-opening metathesis polymerization[36]
Scheme. 2 Synthesis of bottlebrush homopolymers by atom transfer radical polymerization and ring-opening metathesis polymerization[37]
Scheme. 3 Synthesis of bottlebrush homopolymers by ring -opening polymerization and ring-opening metathesis polymerization[40]
Scheme. 4 Synthesis of bottlebrush homopolymers by Grignard metathesis polymerization and ring-opening metathesis polymerization[43]
Fig. 2 Structures of bottlebrush copolymers[3,44]
Scheme. 5 Synthesis of the diblock brush terpolymers[47]
Scheme. 6 Synthesis of heterograft molecular polymer brushes via Janus polymerization and ROMP[65]
Fig. 3 Structures of Janus particles[69]
Scheme. 7 Synthesis of Janus bottlebrush copolymers[67]
Scheme. 8 Synthesis of core-shell bottlebrush copolymers[73]
Fig. 4 Core decomposable core-shell bottlebrush polymers[72,76]
Fig. 5 Adding diluent to control synthesis of bottlebrush polymers[35,81]
Fig. 6 Synthesis of tapered bottlebrush polymers by sequential addition of macromonomers[83]
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