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Progress in Chemistry 2019, Vol. 31 Issue (9): 1283-1292 DOI: 10.7536/PC190219 Previous Articles   Next Articles

Application of MXene and Its Composites in Sodium/Potassium Ion Batteries

Jiahui Li1,2, Jing Zhang1,2, Binglong Rui1,2, Li Lin1,2, Limin Chang1,2,**(), Ping Nie1,2,**()   

  1. 1. Key Laboratory of Preparation and Applications of Environmental Friendly Materials of the Ministry of Education, Jilin Normal University, Changchun 130103, China
    2. College of Chemistry, Jilin Normal University, Siping 136000, China
  • Received: Online: Published:
  • Contact: Limin Chang, Ping Nie
  • About author:
    ** E-mail: (Limin Chang)
    (Ping Nie)
  • Supported by:
    The National Key R&D Program of China(No.SQ2017YFGH001474); The National Natural Science Foundation of China(No.51802111); The National Natural Science Foundation of China(No.51778268); The Natural Science Foundation of Jilin Province(No.20180101192JC); The Funding of Research Program of Jilin Normal University(No.JJKH20190997KJ)
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MXene has attracted considerable attention as a new type of two-dimensional layered structural materials owing to its high electron conductivity, large specific area, excellent mechanical properties and unique layered structure, which make it promising for application in energy storage, catalysis and adsorption. MXene and its composites have recently aroused intense interest for rechargeable batteries. Transition metal sulfides and oxides have the merits of high capacity, however suffering from issues of low conductivity, relatively large volume expansion and poor capacity retention during cycling. Combining MXene with these materials can not only increase the specific capacity, but also enhance electronic conductivity and solve the volume change during electrochemical cycling, finally achieving superior electrochemical properties. This review covers the key technological developments and latest progress of MXene composites in sodium ion batteries and potassium ion batteries. Starting from a brief introduction of the background of sodium ion batteries, potassium ion batteries and MXene, we mainly focus on research progress on synthesis and application in sodium ion batteries, including sulfides, oxides, and carbonaceous materials. The study on potassium ion batteries is still in its infancy. Current status of MXene and its composite in potassium ion batteries have also been summarized, also current challenges and future perspectives in the application of MXene materials are discussed.

Key words: MXene, sodium ion batteries, potassium ion batteries, anode, composites
Fig. 1 The number of published papers from Web of Science(Search time:Jan. 2019) with topics “MXene” and “batteries” from 2013 to 2018
Fig. 2 Schematic for the exfoliation process of MAX phases and formation of MXenes[17].Copyright 2012, American Chemical Society
Fig. 3 (a) Structure of MAX phases and the corresponding MXenes[18];(b) SEM image for Ti3AlC2 after HF treatment(Ti3C2Tx)[17].Copyright 2014, Wiley-VCH; Copyright 2012, American Chemical Society
Fig. 4 (a) Schematic of fabrication process for M’-c-Ti3C2Tx(M+=Li +, Na +, K+, TBA+)by flocculation using MOH;(b) SEM image of Na-c-Ti3C2Tx flocculated networks. Inset shows a higher magnification image;(c) HRTEM image showing stacked layers[49]. Copyright 2018, The Royal Society of Chemistry
Fig. 5 (a) Schematic illustration of the preparation of MXene/SnS2 composite by vacuum-assisted filtration;(b) SEM image of the MXene/SnS2-5∶1;(c, d) HRTEM images of CoS/MXene;(e) The synthesis process of CoS/MXene composite;(f) Cycling performance of MXene/SnS2 10∶1, MXene/SnS2 5∶1, MXene/SnS2 2∶1 and MXene;(g) Rate performance of CoS/MXene at various current densities[43, 44].Copyright 2018, Elsevier; Copyright 2019, Elsevier
Fig. 6 (a, b) TEM images of CoNiO2/Ti3C2Tx;(c) Cycling performance of CoNiO2/Ti3C2Tx composite;(d) Charge-transfer mechanism of CoNiO2/Ti3C2Tx composite[63]. Copyright 2018, Elsevier
Fig. 7 (a) Schematic of the fabrication of M-NTO or M-KTO nanoribbons;(b, c) SEM images of M-KTO(The inset is the photograph of M-KTO powder);(d) HRTEM image of M-KTO(The inset is the corresponding SAED patterns);(e) CV of M-KTO measured at 0.1 mV·s-1;(f) Galvanostatic charge and discharge curves of M-KTO cycled at different current densities[80]. Copyright 2017, American Chemical Society
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