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Progress in Chemistry 2019, Vol. 31 Issue (8): 1148-1158 DOI: 10.7536/PC190131 Previous Articles   Next Articles

Synthesis of the Functionalized Porous Materials and Their Applications in the Specific Recognition and Separation

Qiang Jia, Hongwei Song, Sheng Tang, Jing Wang**(), Yinxian Peng**()   

  1. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China
  • Received: Online: Published:
  • Contact: Jing Wang, Yinxian Peng
  • About author:
    ** E-mail: (Jing Wang)
    (Yinxian Peng)
  • Supported by:
    National Natural Science Foundation of China(21705060); National Natural Science Foundation of China(21605105); Social Development Key Project Fund of Zhenjiang(SH2018011)
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Functionalized porous materials(FPMs) as ideal materials for specific idenpngication and separation have attracted a great deal of attention due to their excellent controllability of preparation, great specific surface area and unique three-dimensional macrostructures with well-defined interconnected porous networks. In this paper, the preparation of FPMs and their applications in specific recognition and separation are reviewed and prospected systematically. Firstly, the basic theory of the preparation of FPMs and the concept of frontier design are expounded systematically. Then, through the in-depth analysis of the preparation principle and key factors during synthesis of FPMs, the mechanism and applications for FPMs in the fields of specific recognition, extraction natural functional ingredients, separation and removal pollutants and catalytic reaction are reviewed. The problems and development trends of FPMs in the fields of specific recognition, catalysis and separation are analyzed and forecasted.

Key words: functionalized porous materials, fabrication methods, catalysis, adsorption
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Fig. 2 Representative molecular structures for networks CMP(0~4)[34].Reprinted with permission from ref. 34. Copyright [2008] American Chemical Society
Fig. 3 Morphological characterizations of the polymer microspheres. SEM(a and b) and TEM(c) micrographs of PMMA Reprinted with permission from ref 47. Copyright [2005] American Chemical Society.
Fig. 4 Schematic illustration for the synthesis of MPMMA by Pickering emulsion polymerization[82]
Fig. 5 Schematic illustration of the synthesis of Cr3+-HPFs-1-H+ and the conversion of carbohydrate into HMF in [Emim]Cl under atmospheric pressure[84]
Fig. 6 Schematic of fabrication process of the Ho-SnO2@MIPs[87]
Fig. 7 The chemical structures of TFSE compound(a), NUS-30(b), NUS-31(c) and NUS-32(d). Reprinted with permission from ref 89. Copyright [2019] American Chemical Society.
Fig. 8 Synthesis of CC10 by [4 + 6] Schiff-base cycloimination reaction[94]
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