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Progress in Chemistry 2019, Vol. 31 Issue (8): 1159-1165 DOI: 10.7536/PC190122 Previous Articles   Next Articles

Catalytic Combustion of VOCs by Manganese-Based Catalysts

Xin Liu1, Yongqiang Wang1,2,**(), Fang Liu1,2, Chaocheng Zhao1, Huaxin Liu1, Lin Shi1   

  1. 1. College of Chemical Engineering, China University of Petroleum(East China), Qingdao 266580, China
    2. State Key Laboratory of Petroleum Pollution Control, China University of Petroleum(East China), Qingdao 266580, China
  • Received: Online: Published:
  • Contact: Yongqiang Wang
  • About author:
    ** E-mail:
  • Supported by:
    Shandong Province Natural Science Foundation(ZR2019EE112); Fundamental Research Funds for the Central Universities(18CX02123A)
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Manganese-based catalysts have shown broad application prospects in the field of catalytic combustion of VOCs as a kind of non-noble metal materials with high catalytic activity, strong stability and low cost. However, there are also some shortcomings about the material, such as weak surface electron transfer ability and low specific surface area. Series of measures are applied in order to overcome these limitations, such as doping modification. In this paper, the recent advances in preparation methods, chemical compositions, morphology and structure of manganese-based catalysts are reviewed from four aspects: single manganese oxide, noble metal doping, supports and perovskite-type catalysts. The future research focus should be the monolith and industrialization of manganese-based catalysts.

Key words: manganese-based catalyst, catalytic combustion, VOCs, modification, perovskite
Table 1 Manganese oxide catalyst by different preparation methods for catalytic combustion of toluene
Catalyst Active site T90(℃) SBET(m2·g-1) Preparation ref Year
MnOx-HT MnO2 210 87.9 hard-template 15 2014
MnOx-PC Mn2O3 280 8.15 precipitation
MnOx-RP Mn2O3 230 36 an alkali-promoted redox precipitation strategy 16 2016
MnOx-SG Mn5O8 250 33 a conventional citrate sol-gel method
a-Mn2O3 Mn2O3 260~275 43 solution combustion synthesis 17 2015
b-Mn3O4 Mn3O4 240~250 46
Mn2O3(A-0) Mn2O3 248 6.4 acid treatment(The number after A represents the acid content) 18 2018
Mn2O3(A-5) 239 9.9
Table 2 Manganese-based oxide catalysts with different pore structures
Catalyst VOCs T90(℃) SBET(m2·g-1) Structure ref Year
1D-MnO2 Ethanol
(300ppm、45 000 h-1)		 190 21 1DOM single crystal nanostructured nonporous material 25 2015
2D-MnO2 160 45 porous materials with 2DOM hexagonal channels
3D-MnO2 150 87 symmetrical 3DOM ordered pore structure
Mn1-600 Naphthalene
(75 000 h-1)		 >315 <1 connected by a series of nanoparticles. 11 2013
Mn2-600 290 7 connected by a series of nanoparticles.
Mn3-600 250 78 ordered network pore structure with pore size between 3~10 nm
α-MnO2 Toluene(1000 ppm、20 000 mL/(g·h) 238 53.1 rod-like tetragonal 23 2012
ε-MnO2 229 30.3 flower-like hexagonal
β-MnO2 241 113.5 dumbbell-like tetragonal
Table 3 Research results of A-substituted perovskite catalysts for VOCs combustion
Catalyst VOCs VOCs conversion temperature(℃) SBET(m2·g-1) ref Year
La0.9K0.1MnO3 Methyl vinyl ketone
(1250 ppmv, 425 h-1)		 267
(100)		 14.4 54 2009
La1-xCaxMnO3 Ethanol
(10 000 h-1)		 230
(100)		 22~26 66 2011
La1-xCaxMnO3 Hexane
(10 000 h-1)		 365
(100)		 22~26 66 2011
3DOM La0.6Sr0.4MnO3 Methane
(3 0000 mL/(g h))		 661~698
(90)		 32~40 67 2013
La0.8Ce0.2MnO3/CeO2 Toluene
(12 000 h-1)		 240~275
(90)		 13~95 68 2016
La0.8Sr0.2MnO3 Phenol
(10 000 h-1)		 300
(100)		 7.35 69 2017
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