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Progress in Chemistry 2019, Vol. 31 Issue (7): 1044-1055 DOI: 10.7536/PC181113 Previous Articles   Next Articles

Ways and Mechanism of Improving the Mechanical Properties of Thermoplastic Starch

Dongdong Zha1, Wen Zhou1, Peng Yin1, Bin Guo1,2,3,**(), Bengang Li1, Yanan Huang2,3   

  1. 1.College of Science, Nanjing Forestry University, Nanjing 210037, China
    2.Agricultural and Forest Products Processing Academician Workstation, Luohe 462600, China
    3.Post-Doctoral Research Center of Nanjiecun Group, Luohe 462600, China
  • Received: Online: Published:
  • Contact: Bin Guo
  • About author:
    ** E-mail:
  • Supported by:
    Jiangsu Government Scholarship for Overseas Studies, the Nanjing Forestry University Yong Top Talent Program, Postgraduate Research &Practice Innovation Program of Jiangsu Province(KYCX19_1108); Natural Science Foundation of Jiangsu Province(BK20140967)
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Great attention has been paid to the biodegradable plastics based on renewable resources(such as starch, cellulose and protein), which is one of the important trends in the development of the degradable plastics industry. Due to its wide source, low cost and biodegradability, natural starch is widely used in the preparation of starch plastics and is used in agriculture, food, medicine and packaging industries, which is expected to replace petroleum-based derived polymers. Starch molecules contain a large amount of hydroxyl groups, which easily form intermolecular hydrogen bonds and intermolecular hydrogen bonds, so as to affect their processing. Adding plasticizer to destroy the crystalline structure of starch can produce thermoplastic starch, but the poor mechanical properties of thermoplastic starch are the primary problem affecting its performance. In recent years, extensive research has been carried out at home and abroad in an attempt to enhance its mechanical properties. In this paper, based on the different classification of thermoplastic starch materials, and with the emphasis on the way to improve the mechanical properties and the mechanism, the research work in recent years to improve the mechanical properties of thermoplastic starch materials is summarized. In addition, the related factors affecting mechanical properties and the ways to improve are introduced, and the key research in this field is also summarized and prospected.

Key words: thermoplastic starch, starch plastic, mechanical property, modified starch, modification by additive
Fig. 1 Mechanism of hydroxypropylation of starch with propylene oxide[17]
Fig. 2 Mechanism of photocrosslinking initiated by sodium benzoate[28]
[1]
Yu L, Christie G . J.Mater. Sci., 2005,40(1):111.
[2]
Teixeira E D M, Pasquini D, Curvelo A A S, Corradini E, Bel-gacem M N, Dufresne A . Carbohydr. Polym., 2009,78(3):422.
[3]
Lecorre D, Bras J, Dufresne A . J.Nanopart. Res., 2011,13(12):7193.
[4]
Xie F W, Pollet E, Peter J . Luc Avérous H. Prog. Polym. Sci., 2013,38(10/11):1590.
[5]
Li M, Witt T, Xie F, Warren F J, Halley P J, Gilbert R G . Carbohydr. Polym., 2015,122(20):115.
[6]
Gary N, Hamzeh Y, Kaboorani A . Ind. Crops Prod., 2018,115:298.
[7]
Sun S, Liu P, Ji N, Hou H, Dong H . Food Hydrocolloids, 2017,72:81.
[8]
Przybytek A, Sienkiewicz M, Lipka J K, Janik H . Ind. Crops Prod., 2018,122(15):375.
[9]
Fonseca L M, Gonçalves J R, Halal S L M E, Pinto V Z, Dias A R G, Jacques A C, Zavareze E R . LWT-Food Sci. Technol., 2015,60(2):714.
[10]
El Halal S L, Colussi R, Pinto V Z, Bartz J, Radunz M, Carreño N L V, Dias A R G, Zavarezea E R . Food Chem., 2015,168(1):247.
[11]
Zhang Y R, Wang X L, Zhao G M, Wang Y Z . Carbohydr. Polym., 2013,96(1):358.
[12]
Fiedorowicz M, Para A . Carbohydr. Polym., 2006,63(3):360.
[13]
Klein B, Vanier N L, Moomand K, Pinto V Z, Colussi R, Zavareze E R, Dias A R G . Food Chem., 2014,155(10):167.
[14]
Colussi R, Pinto V Z, Halal S L E, Biduski B, Prietto L, Castihos D D, Zavareze E R, Dias A R G . Food Chem., 2016,221:1614.
[15]
Larotonda F D S, Matsui K N, Soldi V, Laurindo J B . Braz. Arch. Biol. Technol., 2004,47(3):477.
[16]
Bergel B F, Osorio S D, Luz L M D, Santana R M C . Carbohydrate Polymers, 2018,200(7):106.
[17]
Woggum T, Sirivongpaisal P, Wittaya T . Food Hydrocolloids, 2015,50:54.
[18]
Lee H L, Yoo B . LWT-Food Sci. Technol., 2011,44(3):765.
[19]
Kim H Y, Jane J L, Lamsal B . Ind. Crops Prod., 2017,95:175.
[20]
Qiu L, Hu F, Peng Y . Carbohydr. Polym., 2013,91(2):590.
[21]
Gutiérrez T J, Tapia M S, Pérez E, Famá L . Food Hydrocolloids, 2015,45:211.
[22]
薛灿(Xue C), 银鹏(Yin P), 姜子邓牙(Jiang Z D Y), 郭斌(Guo B), 李盘欣(Li P X) . 塑料 (Plastics), 2017,46(5):46.
[23]
Yeh J T, Hou Y J, Cheng L, Wang Y Z, Yang L, Wang C K . Carbohydr. Polym., 2015,127:135.
[24]
Shah U, Naqash F, Gani A, Masoodi F A . Compre. Rev. Food Sci. Food Saf., 2016,15(3):568.
[25]
Colivet J, Carvalho R A . Ind. Crops Prod., 2017,95:599.
[26]
Sun S, Liu P, Ji N, Hou H, Dong H . Food Hydrocolloids, 2018,77:964.
[27]
Khan B, Niazi M B K, Jahan Z, Farooq W, Naqvi S R, Ali M, Ahmed I, Hussain A . Food Packag. Shelf Life. 2018,6.
[28]
Niazi M B K, Broekhuis A A . Eur. Polym. J., 2015,64:229.
[29]
Zain A H M, Wahab M K A, Ismail H . Polym. Bull., 2018,75(8):3341.
[30]
唐皞(Tang H), 郭斌(Guo B), 薛岚(Xue L), 李盘欣(Li P X), 黄亚男(Huang Y N), 张齐生(Zhang Q S) . 塑料工业 (China Plastics Industry), 2012,40(7):1.
[31]
Ivanič F, Jochec-Mošková D, Janigová I, Chodák I . Eur. Polym. J., 2017,93:843.
[32]
Guzmán M, Murillo E A . Polym. Eng. Sci., 2015,55(11):2526.
[33]
Yan Q, Hou H, Guo P, Dong H . Carbohydr. Polym., 2012,87(1):707.
[34]
Turhan K N, Sahbaz F . J.Food Eng., 2004,61(3):459.
[35]
Chang Y P, Karim A A, Seow C C . Food Hydrocolloids, 2006,20(1):1.
[36]
Zullo R, Iannace S . Carbohydr. Polym., 2009,77(2):376.
[37]
Avérous L, Pollet E . Biofuels Bioprod. Biorefin., 2010,3(3):329.
[38]
Nguyen Vu H P, Lumdubwong N . Carbohydr. Polym., 2016,154:112.
[39]
Wang J L, Cheng F, Zhu P X . Carbohydr. Polym., 2014,101:1109.
[40]
Bendaoud A, Chalamet Y . Carbohydr. Polym., 2013,97(2):665.
[41]
Zhang B, Xie F, Zhang T, Chen L, Li X, Truss R W, Halley P J, Shamshina J L, McNally T, Rogers R D . Carbohydr. Polym., 2016,146:67.
[42]
Zhang K, Cheng F, Lin Y, Zhou M, Zhu P X . Carbohydr. Polym., 2018,195:107.
[43]
Guzmán M, Giraldo D, Murillo E . Polímeros, 2017,27(1):1.
[44]
Müller C M, Laurindo J B, Yamashita F . Carbohydr. Polym., 2012,89(2):504.
[45]
Wilpiszewska K, Antosik A K, Spychaj T . Carbohydr. Polym., 2015,128:82.
[46]
Kaewtatip K, Tanrattanakul V . Mater. Des., 2012,37:423.
[47]
López O, Castillo L, Zaritzky N, Barbosa S, Villar M, Garcia M A . Procedia Mater. Sci., 2015,8:338.
[48]
Castillo L A, López O V, Ghilardi J, Villar M A, Barbosa S E, Garcia M A . Food Hydrocolloids, 2015,51(2):432.
[49]
Ostafińska A, Mikešová J, Krejčíková S, Nevoralová M, Šturcová A, Zhigunov A, Michálková D, Šlouf M . Int. J. Biol. Macromol., 2017,101:273.
[50]
Oleyaei S A, Zahedi Y, Ghanbarzadeh B, Moayedi A A . Int. J. Biol. Macromol., 2016,89:256.
[51]
Cao Z, Daly M, Geever L M, Major I, Higginbotham C L, Devine D M . Composites Part B, 2016,94:312.
[52]
Shanmugam N, Hussein I A, Badghaish A, Shuaib A N, Furquan, S A, Al-Mehthel M H . Polym. Degrad. STab., 2015,112:94.
[53]
Sundum T, Szécsényi K M, Kaewtatip K . Carbohydr. Polym., 2018,191:198.
[54]
Javanbakht S, Namazi H . Carbohydr. Polym., 2017,176:220.
[55]
Ma T, Chang P R, Zheng P, Ma X . Carbohydr. Polym., 2013,94(1):63.
[56]
Ferreira W H, Andrade C T . Ind. Crops Prod., 2015,77:684.
[57]
Bénézet J C, Stanojlovic-davidovic A, Bergeret A, Ferry L, Crespy A . Ind. Crops Prod., 2012,37(1):435.
[58]
Prabhakar M N, Rehman Shah A U, Song J I . Carbohydr. Polym., 2017,168:201.
[59]
Prachayawarakorn J, Chaiwatyothin S, Mueangta S, Hanchana A . Mater. Des., 2013,47:309.
[60]
Prachayawarakorn J, Ruttanabus P, Boonsom P . J.Polym. Environ., 2011,19(1):274.
[61]
Johar N, Ahmad I, Dufresne A . Ind. Crops Prod., 2012,37(1):93.
[62]
Kargarzadeh H, Johar N, Ahmad I . Compos. Sci. Tech., 2017,151:147.
[63]
唐皞(Tang H), 姜海天(Jiang H T), 王礼建(Wang L J), 范磊(Fan L), 郭斌(Guo B), 李盘欣(Li P X), 张齐生(Zhang Q S) . 塑料工业 (China Plastics Industry), 2013,41(9):110.
[64]
Guo B, Wang L J, Yin P, Li B G, Li P X . J.Thermoplast. Compos. Mater., 2017,30(4):564.
[65]
郭斌(Guo B), 查东东(Zha D D), 薛灿(Xue C), 银鹏(Yin P), 李盘欣(Li P X) . 功能高分子学报 (Journal of Functional Polymers), 2018. 31(2):68.
[66]
Lin S P, Han J L, Yeh J T, Chang F C, Hsiehab K H . Eur. Polym. J., 2007,43(3):996.
[67]
Jantanasakulwong K, Leksawasdi N, Seesuriyachan P, Wongsuriyasak S, Techapun C, Ougizawa, T . Eur. Polym. J., 2016,84:292.
[68]
Mendes J F, Paschoalin R T, Carmona V B, Sena Neto A R, Marques A C P, Marconcini J M, Mattoso L H C, Medeiros E S, Oliveira J E . Carbohydr. Polym., 2016,137:452.
[69]
Bof M J, Bordagaray V C, Locaso D E, Garcia M A . Food Hydrocolloids, 2015,51:281.
[70]
Ren L, Yan X, Zhou J, Tong J, Su X . Int. J. Biol. Macromol., 2017,105(3):1636.
[71]
Zamudio-Flores P B, Torres A V, Salgado-Delgado R, Bello-Pérez L A . J.Appl. Polym. Sci., 2010,115(2):991.
[72]
Chinma C E, Ariahu C C, Abu J O . Int. J. Food Sci. Technol., 2012,47(2):383.
[73]
García L, Cova A, Sandoval A J, Müller A J, Carrasquel L M . Carbohydr. Polym., 2012,87(2):1375.
[74]
Sun Q, Sun C, Xiong L . Carbohydr. Polym., 2013,98(1):630.
[75]
Azevedo V M, Borges S V, Marconcini J M, Yoshida M I, Sena Neto A R, Pereira T C, Pereira C F G . Carbohydr. Polym., 2016,157:971.
[76]
Tihminlioglu F, Atik I D, Özen B . J.Appl. Polym. Sci., 2010,119(1):235.
[77]
Qiu C, Li X, Ji N, Qin Y, Sun Q, Xiong L . Food Hydrocolloids, 2015,48:1.
[78]
Gao P, Wang F, Gu F, Ning J, Liang J, Li N, Ludescher R D . Carbohydr. Polym., 2017,157:1254.
[79]
Rhim J W, Wang L F . Carbohydr. Polym., 2013,96(1):71.
[80]
Jumaidin R, Sapuan S M, Jawaid M, Ishak M R, Sahari J . Int. J. Biol. Macromol., 2016,89:575.
[81]
Wu Y, Geng F, Chang P, Yu J, Ma X . Carbohydr. Polym., 2009,76(2):299.
[82]
Cao X, Chang P R, Huneault M A . Carbohydr. Polym., 2008,71(1):119.
[83]
Yu L, Dean K, Li L . Prog. Polym. Sci., 2006,31(6):576.
[84]
Ortega-Toro R, Contreras J, Talens P, Chiralt A . Food Packag. Shelf Life, 2015,5:10.
[85]
Correa A C, Carmona V B, Simão J A, Mattoso L H C, Marconcini J M . Carbohydr. Polym., 2017,167:177.
[86]
Koh J J, Zhang X, He C . Int. J. Biol. Macromol., 2018,109:99.
[87]
Müller C M O, Pires A T N, Yamashita F . J.Braz. Chem. Soc., 2012,23(3):426.
[88]
Moghaddam M R A, Razavi S M A, Jahani Y . J.Polym. Environ., 2018: 1.
[89]
He Y S, Zeng J B, Li S L, Wang Y Z . Thermochim. Acta, 2012,529(1):80.
[90]
Li J, Luo X, Lin X, Zhou Y . Starch-Stärke, 2013,65(9/10):831.
[91]
Liu D, Qi Z, Zhang Y, Xu J, Guo B . Starch-Stärke, 2015,67(9/10):802.
[92]
Zeng J B, Jiao L, Li Y D, Srinivasan M, Li T, Wang Y Z . Carbohydr. Polym., 2011,83(2):762.
[93]
Jiang X, Li H, Luo Y, Zhao Y, Hou L . Int. J. Biol. Macro-mol., 2016,82:223.
[94]
Tian H, Yan J, Rajulu A V, Xiang A, Luo X . Int. J. Biol. Macromol., 2017,96:518.
[95]
Xu P, Zeng Q, Ying C, Ma P, Dong W, Chen M . Carbohydr. Polym., 2017,174:716.
[96]
Reddy C S K, Ghai R, Rashmi, Kalia V C . Bioresour. Technol., 2003,87(2):137.
[97]
Thire R M S M, Ribeiro T A A, Andrade C T . J.Appl. Polym. Sci., 2010,100(6):4338.
[98]
Rivera-Briso A L, Serrano-Aroca Á . Polym., 2018,10, 732
[99]
Malmir S, Montero B, Rico M, Barral L, Bouza R, Farrag Y . Carbohydr. Polym., 2018,194:357.
[100]
Ramsay B A, Langlade V, Carreau P J, Ramsay J A . Appl. Environ. Microbiol., 1993,59(4):1242.
[101]
Olivato J B, Marini J, Pollet E, Yamashita F, Grossmann M V E, Avérousc L . Carbohydr. Polym., 2015,118:250.
[102]
Nunes M A B S, Marinho V A D, Falcão G A M, Canedo E L, Bardi M A G, Carvalho L H . Polym. Test. 2018,70, 281.
[103]
Fourati Y, Tarrés Q, Mutjé P, Boufi S . Carbohydr. Polym. 2018,199:51.
[104]
Sabetzadeh M, Bagheri R, Masoomi M . J.Appl. Polym. Sci., 2012,126(S1):E63
[105]
Raee E, Kaffashi B . J.Appl. Polym. Sci., 2017,135(4):45740.
[106]
Gutiérrez T J, Alvarez V A . React. Funct. Polym., 2017,112:33.
[107]
Oromiehie A R, Lari T T, Rabiee A . J.Appl. Polym. Sci., 2012,127(2):1128.
[108]
Martins A B, Santana R M . Carbohydr. Polym., 2016,135:79.
[109]
Schlemmer D, Oliveira E R D, Sales M J A . J. Therm. Anal. Calorim., 2007,87(3):635. http://link.springer.com/10.1007/s10973-006-7776-y

doi: 10.1007/s10973-006-7776-y
[110]
Berruezo M, Ludueña, L N, Rodriguez E, Alvarez, V A . J. Plast. Film Sheeting, 2014,30(2):141.
[111]
孙晓巍(Sun X W), 台立民(Tai L M) . 中国塑料 (China Plastics), 2008,( 10):38.
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