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Progress in Chemistry 2019, Vol. 31 Issue (4): 536-549 DOI: 10.7536/PC180933 Previous Articles   Next Articles

Colorimetric and Fluorogenic Chemosensors for Mercury Ion Based on Nanomaterials

Yang Shen1, Jiwen Hu2, Tingting Liu1, Hongwen Gao1,**(), Zhangjun Hu2,**()   

  1. 1. College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China
    2. College of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
  • Received: Online: Published:
  • Contact: Hongwen Gao, Zhangjun Hu
  • About author:
    ** E-mail:(Hongwen Gao)
    ** E-mail:(Zhangjun Hu)
  • Supported by:
    National Natural Science Foundation of China(21577098); Shanghai Natural Science Foundation(17ZR1410500)
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Mercury ion(Hg2+) is one of the most toxic heavy metals that has severe adverse effects on the environment and humans. Therefore, more and more attention has been paid to developing analytical approaches for the rapid detection of Hg2+. Nanomaterials are widely used for Hg2+ detection due to their potential optical advantages and stability. The nanosensors for Hg2+in recent years are highlighted in this review. According to the composition of nanomaterials, these sensors can be divided into nanosensors based on gold, silver, carbon and silicon nanomaterials, quantum dots, organic nanoparticles and other nanomaterials. These nanosensors are described and discussed respectively in terms of design principle, identification performance and practical application. Finally, the research prospect in this field is presented.

Key words: Hg2+, nanomaterials, fluorescence, colorimetry, sensor
Fig. 1 Schematic illustration for the sensing mechanism of Hg2+ sensor based on AuNPs[32]. Copyright 2018, Elsevier.
Fig. 2 Schematic illustration for the sensing mechanism of Hg2+ sensor based on AuNPs[34]
Fig. 3 Schematic illustration for the sensing mechanism of Hg2+ sensor based on AuNCs[40]. Copyright 2018, Elsevier.
Fig. 4 Schematic illustration for the sensing mechanism of Hg2+ sensor based on AuNCs[41]
Fig. 5 Schematic illustration for the sensing mechanism of Hg2+ sensor based on AuNCs[42]
Fig. 6 Schematic illustration for the sensing mechanism of Hg2+ sensor based on AgNPs[51]
Fig. 7 Schematic illustration for the sensing mechanism of Hg2+ sensor based on AgNCs[53]
Fig. 8 Schematic illustration for the sensing mechanism of Hg2+ sensor based on CH3NH3PbBr3 QDs[61].Copyright 2018, Elsevier.
Fig. 9 Schematic illustration for the sensing mechanism of Hg2+ sensor based on ZnSe QDs[62]
Fig. 10 Schematic illustration for the sensing mechanism of Hg2+ sensor based on CdTe QDs[63]. Copyright 2018, Elsevier.
Fig. 11 Schematic illustration for the sensing mechanism of Hg2+ sensor based on CQDs[69]
Fig. 12 Schematic illustration for the sensing mechanism of Hg2+ sensor based on Cyt-dot[70]
Fig. 13 Schematic illustration for the sensing mechanism of Hg2+ sensor based on CDs[71]
Fig. 14 Schematic illustration for the sensing mechanism of Hg2+ sensor based on CDs[72]
Fig. 15 Schematic illustration for the sensing mechanism of Hg2+ sensor based on CDs[74]. Copyright 2018, Elsevier.
Fig. 16 Schematic illustration for the sensing mechanism of Hg2+ sensor based on rGO[75]
Fig. 17 Schematic illustration for the sensing mechanism of Hg2+ sensor based on organic nanoparticles[91]
Fig. 18 Schematic illustration for the sensing mechanism of Hg2+ sensor based on Fe3O4 nanoparticles[102]. Copyright 2018, Elsevier.
Fig. 19 Schematic illustration for the sensing mechanism of Hg2+ sensor based on TiO2 nanomaterial[105]
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