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Progress in Chemistry 2018, Vol. 30 Issue (12): 2012-2024 DOI: 10.7536/PC180446 Previous Articles   

• Review •

Application of the Tianium, Nickel and Iron Complexes in the Hydrosilylation

Xiaoling Yang, Ying Bai*, Jiayun Li, Zinan Dai, Jiajian Peng*   

  1. Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the Natural Science Foundation of Zhejiang Province(No.LY18B020012) and the Zhejiang Provincial Technologies R&D Program of China(No.2017C31105).
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Tianium, nickel and iron complexes as catalysts have been widely applied in numerous catalytic organic reactions, in which these complexes show excellent catalytic performance and have been recognized as very important research field. We summarize the recent progress in the synthesis of titanium, nickel and iron complexes and their application in the catalytic hydrosilylation of alkenes, alkynes, carbonyl compounds and other unsaturated double bond, triple bond compounds. Furthermore, the deficiencies of the catalysts have been discussed. At last, the future development and prospects of these complexes as catalysts are also proposed.
Contents
1 Introduction
2 Application of the tianium complexes in the hydrosilylation
3 Application of the nickel complexes in the hydrosilylation
4 Application of the iron complexes in the hydrosilylation
5 Conclusion
Key words: non-noble metal, catalysis, hydrosilylation

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