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Progress in Chemistry 2018, Vol. 30 Issue (12): 1992-2002 DOI: 10.7536/PC180406 Previous Articles   Next Articles

• Review •

The Structure of Hexaaluminate and Application in High-Temperature Reaction

Yanyan Zhu1*, Zongyang Yue1, Wen Bian1, Ruilin Liu1, Xiaoxun Ma1, Xiaodong Wang2*   

  1. 1. School of Chemical Engineering, Northwest University, International Scientific and Technological Cooperation Base of MOST for Clean Utilization of Hydrocarbon Resources, Chemical Engineering Research Center of the Ministry of Education for Advanced Use Technology of Shanbei Energy, Shaanxi Research Center of Engineering Technology for Clean Coal Conversion, Collaborative Innovation Center for Development of Energy and Chemical Industry in Northern Shaanxi, Xi'an 710069, China;
    2. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No. 21303137, 21536009, 21676269) and Cyrus Tang Foundation.
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Hexaaluminate materials exhibit remarkable thermal stability due to their peculiar layered structure. The Al3+ ions in the hexaaluminate lattice can be substituted by transition or noble metals, giving rise to redox centers for a variety of reactions. Oxygen in the mirror plane of hexaaluminate is loosely packed, making it a preferential diffusion route of oxygen. All of these favor the application of hexaaluminate in high-temperature oxygen-involved reaction. In this review, the structure of hexaaluminate is firstly introduced. Furthermore, the effect of structure type(magnetoplumbite and β-Al2O3) and metal substitution on the microstructure of hexaaluminate (especially metal chemical state) are carefully described. Then we discuss recent advances of hexaaluminate in high-temperature oxygen-involved reactions, such as, catalytic combustion of CH4, process-gas N2O abatement, decomposition of N2O as a propellant, CH4 chemical looping combustion and reforming, with a special emphasis on the relationship between the microstucture and reaction performance. At last, a brief summary and an outlook are given.
Contents
1 Introduction
2 Crystal structure of hexaaluminate
2.1 Structural type and metal substitution
2.2 Anisotropic crystal growth and preferential diffusion of oxygen
3 Effect of metal substitution on microstructure of hexaaluminate
3.1 Substitution of large cations in the mirror plane
3.2 Substitution of Al3+ ions by transition metal ions
3.3 Substitution of Al3+ ions by noble metal ions
4 High temperature application of hexaaluminate
4.1 Catalytic combustion of methane
4.2 Catalytic decomposition of nitrous oxide
4.3 Chemical looping combustion and reforming of methane
5 Conclusion and outlook
Key words: hexaaluminate, metal substitution, high-temperature catalysts, oxygen carriers, catalytic combustion, N2O decomposition, chemical looping, relationship between structure and reaction performance

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