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Progress in Chemistry 2018, Vol. 30 Issue (11): 1634-1645 DOI: 10.7536/PC180335 Previous Articles   Next Articles

• Review •

Synthesis of Poly(Ester Amide)

Han Gao1, Jun Xu3, Xin Hu2*, Ning Zhu1*, Kai Guo1*   

  1. 1. College of Biotechnology and Pharmaceutical Engineering, State Key Laboratory of Material Chemistry Engineering, Nanjing Tech University, Nanjing 211800, China;
    2. College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211800, China;
    3. Caprolactam Division, SINOPEC Baling Company, Yueyang 414000, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No. 21878145, 21504039, 21522604, U1463201) and the Jiangsu Synergetic Innovation Center for Advanced Bio-Manufacture(No. XTD1823, XTD1821, XTB1802).
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Poly(ester amide)(PEA) is a class of functional polymers with both amide and ester linkages in the polymer main chains. Due to the outstanding biodegradability, biocompatibility and mechanical property, PEA has broad applications in drug delivery, tissue engineering and thermoplastic elastomer. Polycondensation is the original synthetic method to PEA. Recently, remarkable achievements have been made in synthesis of PEA via ring-opening polymerization(ROP). This review summarizes the progress in ROP of cyclic monomers, ring-opening copolymerization(ROCP) of cyclic monomers and ROCP of cyclic/linear momomers. Moreover, multicomponent polymerization(MCP) is highlighted as a novel synthetic strategy to prepare PEA. The challenge and outlook of PEA are also discussed.
Contents
1 Introduction
2 Synthesis of poly(ester amide)s by ring-opening polymerization
2.1 Homo-polymerization of cyclic monomer
2.2 Co-polymerization of cyclic monomer
2.3 Co-Polymerization of cyclic monomer and linear monomer
3 Synthesis of poly(ester amide)s by multicomponent polymerization
4 Conclusion
Key words: poly (ester amide), ring-opening polymerization, multicomponent polymerization

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Abstract

Synthesis of Poly(Ester Amide)