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Progress in Chemistry 2019, Vol. 31 Issue (1): 156-166 DOI: 10.7536/PC180309 Previous Articles   Next Articles

• Review •

Chemical and Physical Mechanism of Water Resistance for Thermoplastic Starch

Dongdong Zha1, Bin Guo1,2,3,**(), Bengang Li1, Peng Yin1, Panxin Li2,3   

  1. 1. College of Science, Nanjing Forestry University, Nanjing 210037, China
    2. Agricultural and Forest Products Processing Academician Workstation of Henan Province, Luohe 462600, China
    3. Post-Doctoral Research Center of Nanjiecun Group, Luohe 462600, China
  • Received: Revised: Online: Published:
  • Contact: Bin Guo
  • About author:
    ** Corresponding author e-mail:
  • Supported by:
    The work was supported by the Jiangsu Government Scholarship for Overseas Studies; The Nanjing Forestry University Young Top Talent Program; The Natural Science Foundation of Jiangsu Province(BK20140967)
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The shortage of oil resources and the need to reduce the environmental burden caused by petroleum-based polymers have driven the development and production of biodegradable materials. In recent decades, natural polymers have replaced current synthetic polymers due to their non-toxicity, biodegradability, and biocompatibility. Starch has been extensively studied for the manufacture of biodegradable composites due to its reproducibility, biodegradability, low cost, and availability, which has been widely used for applications in agriculture, alimentary, medicine and packaging industry. However, the polyhydroxyl structure of starch gives it strong hydrophilicity, and the moisture sensitivity limits their mechanical properties and affects their application. In this paper, mainly from the perspective of improving the physical and chemical effects of thermoplastic starch, the research works in recent years on improving the water resistance of thermoplastic starch material and reducing its sensitivity to environmental humidity are summarized. The related factors affecting the water resistance and the methods of improvement are introduced, and the research trend in this field is also proposed.

Key words: thermoplastic starch, water resistance, chemical modification, physical modification, surface modification
Fig.1 Plasticizing mechanism of starch
Fig.2 The esterification mechanism of acetic acid, maleic anhydride, and caprylyl chloride with starch
Fig.3 Schematic illustrations of citric acid, glycerol, starch and possible structure of crosslinked system[24]
Fig.4 Schematic representation of hydrogen bonding promoted by CN in S/PVA/CN nanocomposite[75]
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