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Progress in Chemistry 2018, Vol. 30 Issue (6): 737-752 DOI: 10.7536/PC171110 Previous Articles   Next Articles

• Review •

Supramolecular Chiral Self-Assembly Based on Small Molecular Natural Products

Yuxia Gao1,2, Yun Liang1, Jun Hu3*, Yong Ju1*   

  1. 1. Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China;
    2. College of Science, China Agricultural University, Beijing 100094, China;
    3. Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No.21472108,21604085,21772112),the National Key R&D Program of China (No.2017YFD0200302),and the Jilin Science Foundation for Youths (No.20160520135JH).
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Supramolecular chirality, one of the most fascinating phenomena in nature and life, can be generated from orderly molecular self-assembly under non-covalent interactions, and plays an important role in life science, pharmaceutical chemistry, and materials science. Natural products, which are abundant in nature, have attracted immense attention in supramolecular chirality due to their unique stereostructures and multiple chiral centers. By transferring and magnifying the molecular chirality into supramolecular assemblies, natural products have been regarded as one of the ideal building blocks in fabricating supramolecular chiral nanostructures. The study of chiral assembly behavior of natural products will not only expand their applications in supramolecular chemistry, but also help us better understand the chiral phenomena in nature and life. In this review, recent developments of supramolecular chiral self-assembly based on small molecular natural products, such as steroids, triterpenoids, amino acids, sugars, and so on, are summarized and their prospects are discussed.
Contents
1 Introduction
2 Chiral self-assembly based on small molecular natural products
2.1 Chiral self-assembly of steroids
2.2 Chiral self-assembly of triterpenoids
2.3 Chiral self-assembly of amino acids
2.4 Chiral self-assembly of sugars
2.5 Chiral self-assembly of other natural products
3 Conclusion
Key words: small molecular natural products, chirality, self-assembly, non-covalent interactions

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