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Progress in Chemistry 2018, Vol. 30 Issue (1): 112-123 DOI: 10.7536/PC171008 Previous Articles   Next Articles

• Review •

Fabrication, Properties and Applications of Functional Surface Based on Polybenzoxazine

Changlu Zhou, Zhong Xin*   

  1. Shanghai Key Laboratory of Multiphase Materials Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21776091, 21506062) and the Program of Leading Talents (2013).
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Polybenzoxazines are well known to be advanced thermoset resin with many unique properties. More specially, the last decade has witnessed active research on various polybenzoxazines based functional surfaces due to their ability of low surface free energy, which can be lower than the widely regarded low surface energy polymer, Teflon, without having fluorine atoms. Nowadays, researches on polybenzoxazine-based functional surfaces have aroused attention in many fields of applications, such as anticorrosion, anti-ice, anti-sticking, liquid manipulation, oil/water separation, and self-cleaning. It is evident that the performance of polybenzoxazine based composites is determined by the chemical structures and constitution. The relationship between structures and surface properties in composites based on polybenzoxazines plays a vital role in the development of advanced surface materials. Herein, the advances in fabricating and investigating performance of functional surfaces based on polybenzoxazines and their composites is reviewed, focusing on the molecule design and fabricating principals of the surfaces with controllable structure, wettability, adhesion, and other fascinating functionality. Current progress from the research database are also summarized along with challenges in the development of polybenzoxazine based functional surface, in order to provide guidelines for designing and developing of materials based on polybenzoxazines with desired properties.
Contents
1 Introduction
2 Fabrication and properties of functional surface based on polybenzoxazine
2.1 Polybenzoxazines chemical structure and surface properties
2.2 Composites' chemical constitution and surface properties
3 Applications of functional surface based on polybenzoxazine
3.1 Anti-corrosion
3.2 Anti-ice
3.3 Anti-sticking
3.4 Liquid manipulation
3.5 Water/oil separation
3.6 Self-cleaning
4 Conclusion
Key words: polybenzoxazine, functional surface, superhydrophobic, wettability:corrosion protection

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