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Progress in Chemistry 2018, Vol. 30 Issue (2/3): 314-324 DOI: 10.7536/PC171007 Previous Articles   

• Review •

Preparation of 5-Hydroxymethylfurfural from Glucose

Yunchao Feng, Miao Zuo, Xianhai Zeng*, Yong Sun, Xing Tang, Lu Lin*   

  1. College of Energy, Fujian Engineering and Research Center of Clean and High-Valued Technologies for Biomass, Xiamen Key Laboratory of High-Valued Conversion Technology of Agricultural Biomass, Xiamen University, Xiamen 361102, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No.21506177, 21676223), the Fujian Provincial Development and Reform Commission, China(No. 2015489), the Fundamental Research Funds for the Central Universities(No.20720160077, 20720160087, 20720170062), the Natural Science Foundation of Fujian Province of China(No.2016J01077, 2015J05034), and the Education Department of Fujian Province(No. JZ160398).
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Biomass derived 5-hydroxymethylfurfural(HMF) has emerged as an important and versatile platform compound containing furan, hydroxymethyl and aldehyde groups to realize the goal for production of several high value added products, such as levulinic acid, 2,5-dimethylfuran, 2,5-furan dicarboxylic acid, 2,5-furan dimethanol, γ-valerolalactone, 5-aminolevulinic acid, which could be served as biofuels, fuel additives, bulk polymer monomers, chemicals and pharmaceuticals. Moreover, glucose is a bulk six-carbon monosaccharide from cellulose by hydrolyzation, and the preparation of HMF from glucose is one of the most effective and promising routes to maximize the utilization of sustainable biomass resources. In this review, focus is primarily put on the recent advances of systematically characterization on catalysts of HMF production from glucose for its activity, stability and application prospect. Then, the various solvent systems used in HMF production in recent years, such as single-phase solvents, biphasic solvents, ionic liquids and deep eutectic solvents, are reviewed and discussed. Finally, the future research directions such as an innovative catalyst, deep eutectic sol-vents are proposed, which might be helpful for researchers.
Contents
1 Introduction
2 Catalysts
2.1 Homogeneous catalysts
2.2 Heterogeneous catalysts
3 Reaction solvents
3.1 Single-phase solvents
3.2 Biphasic solvents
3.3 Ionic liquids
3.4 Deep eutectic solvents
4 Conclusion
Key words: 5-hydroxymethylfurfural, glucose, system of catalysts, reaction system of solvents

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