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Progress in Chemistry 2017, Vol. 29 Issue (12): 1462-1470 DOI: 10.7536/PC170742 Previous Articles   Next Articles

• Review •

Tridentate Titanium Precatalysts Toward Olefin Polymerization

Shifang Yuan1,2,3*, Lijing Wang1,2, Qiuyue Zhang2,3, Wenhua Sun3*   

  1. 1. Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, China;
    2. School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China;
    3. Key Laboratory of Engineering Plastics, lnstitute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21101101, U1362204) and the Scientific Instrument Center of Shanxi University.
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Titanium-based catalysts have been not only providing major catalyses in conventionally producing massive polyolefins with low cost as well as good properties, but also advancing the properties of new polyolefins for new plastic materials. Therefore it has been a core consideration of finely tuning the structures of titanium complexes and enhancing catalytic performances of the olefin polymerization. Besides metallocene catalysts, titanium complexes bearing multi-dentate ligands have been maintained as hot topics, in which tridentate ligands positively stabilize titanium complexes. Meanwhile variations of coordination atoms of those ligands greatly enrich the syntheses and manipulation of the catalytic activity of complexes, therefore controlling the polymerization activity as well as improving the microstructures and properties of resultant polyolefin materials. Herein the recent progress of titanium complexes bearing tridentate ligands have been reviewed toward olefin polymerization, focusing on the electronic and steric influences of substituents within ligands on their catalytic activities and properties of resultant polyolefins. The observations would be helpful to design titanium complexes and correlations between activities of complexes and structures of ligands used.
Contents
1 Introduction
2 Titanium complexes
2.1 Half-titanocene complexes
2.2 Cp-containing Schiff-base titanium complexes
2.3 Complexes based on C, N, X imine ligands
2.4 Complexes based on O, P, N imine ligands
2.5 Complexes based on O, S, N imine ligands
2.6 Complexes based on O, N, N imine ligands
2.7 Complexes based on O, N, O imine ligands
2.8 Complexes based on N, C, N imine ligands
2.9 Complexes based on N, N, S imine ligands
2.10 Bis(aryloxide)s with one additional donors
2.11 Bis(aryloxide)s with two additional donors
2.12 Complexes with other ligands
3 Conclusion
Key words: olefin polymerization, titanium complex, tridentate ligand, catalytic performance

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