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Progress in Chemistry 2018, Vol. 30 Issue (2/3): 286-294 DOI: 10.7536/PC170729 Previous Articles   Next Articles

• Review •

The Classification of Electrofluorochromism Materials and Color Change Mechanisms

Jin Du1, Rui Liao1, Xinglin Zhang1, Huibin Sun1*, Wei Huang1,2   

  1. 1. Key Laboratory of Flexible Electronics & Institute of Advanced Materials, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 211816, China;
    2. Key Laboratory for Organic Electronics & Information Displays, Institute of Advanced Materials, Nanjing University of Posts & Telecommunications, Nanjing 210023, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No. 21504040) and the Natural Science Foundation of Jiangsu Higher Education Institutions(No. 15KJB150012).
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Electrofluorochromism(EFC) refers to a phenomenon that luminescence color of materials can be tuned by the application of an extra electric field, of which the fluorescence is generally switched between ON/OFF or different colors under an electrical stimulus. These materials have received increasing attention because of their extensive applications in ion sensing, information display, bioanalysis, optical imaging, information storage and so on. It is rather remarkable that EFC materials are considered to be prospective smart materials because they can convert electrical signals to more intuitive visual signals. Herein recent research progress in electrofluorochromism field are reviewed, which mainly elaborates the main EFC materials including dyads, fluorophores and polymers(including conjugated polymers) and their emission-color changing mechanism. Structure features of those EFC materials and their functional realization principles in specific applications are highlighted. Those materials have high luminescence contrast, fast response rate, long term stability and exhibit multicolor emissions switching of fluorescence and a number of advantages and have found applications in organic optoelectronic devices field. At the end of the paper, a brief overview of the future directions of this research field is also presented.
Contents
1 Introduction
2 Electrofluorochromism mechanism
3 Classification of electrofluorochromism materials
3.1 Dyads
3.2 Electroswitchable fluorophores
3.3 Fluorescent conjugated polymers
4 Conclusion
Key words: electrochromism, electrofluorochromism(EFC), sensing, conjugated polymer, organic electronic materials

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