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Progress in Chemistry 2017, Vol. 29 Issue (10): 1206-1214 DOI: 10.7536/PC170619 Previous Articles   Next Articles

Special Issue: 电化学有机合成; 金属有机框架材料

• Review •

The Electrochemical Sensors Based on MOF and Their Applications

Xinxin Jiang, Chengjun Zhao, Chunju Zhong, Jianping Li*   

  1. Guangxi Key Laboratory of Electrochemical and Magnetochemical Function Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21375031, 21765006), the Natural Science Foundation of Guangxi Province, China (No. 2015GXNSFFA139005), and the High Level Innovation Teams of Guangxi Colleges & Universities and Outstanding Scholars Program, China (No. Guijiaoren[2014]49).
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Metal organic framework is a kind of three-dimensional framework porous materials self-assembly by a structure of organic ligands and metal centers. Because of the structure of metal organic complex framework, it has good chemical properties. Metal-organic frameworks have become more and more mature when applied to material analysis. Significant progress has also been achieved in the application of electrochemical sensors. In this paper, the newly found preparing approaches to the mental-organic frameworks, constructing electrochemical sensor methods as well as the summary of its application in electrochemical sensor based on MOF are presented. The problems and the limitations in metal-organic frameworks application to the electrochemical sensors are also involved. At the end, we briefly discuss the direction and expectations of electrochemical sensor based on metal-organic frameworks.
Contents
1 Introduction
2 Methods for preparing MOF modified electrode
2.1 Layer-by-Layer self-assembly
2.2 Electro polymerization
2.3 Solvothermal Method
3 The role of MOF in electrochemical sensor
3.1 Catalysis
3.2 Improvement of surface areas
3.3 Electroactive immobilization
3.4 Molecular recognition
4 Application in electrochemical sensor about MOF
4.1 Application in the determination of organics
4.2 Application in the determination of inorganic ions
4.3 Application in the determination of biomacromolecules
5 Conclusion
Key words: metal-organic framework, sensitive membrane, electrochemical sensors, porous materials

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