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Progress in Chemistry 2017, Vol. 29 Issue (11): 1422-1434 DOI: 10.7536/PC170560 Previous Articles   

Special Issue: 电化学有机合成

• Review •

Preparation and Application of Nanometer NCS in Electrochemical Energy Conversion and Storage

Yongming Zhu, Yunpeng Jiang, Huili Hu*   

  1. Falcuty of Applied Chemistry, Harbin Institute of Technology, Weihai 264209, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the Major Program of Shandong Province, China(No. 2015ZDZX04002).
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Nickel-cobalt bimetallic sulfide (NiCo2S4) has a typical AB2O4 spinel structure. The conductivity of NiCo2S4 is two orders of magnitude higher than that of NiCo2O4, and its conductivity is 1.25×106 S·m-1at room temperature. In addition, NiCo2S4 provides a more efficient redox reaction than the corresponding one-component sulfide, and has great potential for its unique nanostructures and electrochemical properties. In this paper, the preparation of NiCo2S4 nanostructures and its application in electrochemical energy conversion and storage are reviewed. The morphology, physicochemical properties and synthesis methods of NiCo2S4 nano materials are introduced. Pretreatment conditions, preparation methods and growth matrix will have an effect on the morphology and properties of NiCo2S4 nanostructures. NiCo2S4 with different nanostructures (such as nanoneedles, nanowires, nanorods, nanotubes, nanocapses, nanosheets, nanostructures and hierarchical structures) can be prepared by a variety of methods (such as hydrothermal method and solvent heat method, low temperature synthesis method, anion exchange method, steam conversion method, electrodeposition method, coprecipitation method and self-assembly, etc.). Among them, hydrothermal and solvothermal are the most commonly used methods because they have the characteristics of low cost, easy handling and suitable for large scale manufacturing. The application status of NiCo2S4 nano materials in electrocatalysis, supercapacitors and lithium ion batteries is summarized. This paper analyzes and compares the preparation process, method and application of different nanostructures, hoping to promote the development of NiCo2S4 nano materials in the field of electrochemical energy conversion and storage. The development and application direction of NiCo2S4 nano materials are proposed.
Contents
1 Introduction
2 Preparation of NiCo2S4 nanostructures
3 Electrochemical application of NiCo2S4 nanostructures
3.1 Electrochemical catalysis:bifunctional electrocatalysts
3.2 Pseudocapacitive properties:supercapacitors
3.3 New electrode materials:anode material for Li-ion batteries
4 Conclusion
Key words: NiCo2S4, electrode materials, morphology and properties, preparation

CLC Number: 

[1] Han S C, Hu L F, Gao N, Al-Ghamdi A A, Fang X S. Advanced Functional Materials, 2014, 24(24):3725.
[2] Xu X J, Hu L F, Gao N, Liu S X, Wageh S, Al-Ghamdi A A, Alshahire A, Fang X S. Advanced Functional Materials, 2015, 25(3):445.
[3] Han S, Wu D Q, Li S, Zhang F, Feng X L. Small, 2013, 9(8):1173.
[4] Xiao J W, Yang S H. RSC Advances, 2011, 1(4):588.
[5] Wei T Y, Chen C H, Chien H C, Lu S Y, Hu C C. Advanced Materials, 2010, 22(3):347.
[6] Chen H C, Jiang J J, Zhang L, Wan H Z, Qi T, Xia D D. Nanoscale, 2013, 5(19):8879.
[7] Xiao J W, Zeng X W, Chen W, Xiao F, Wang S. Chemical Communications, 2013, 49(100):11734.
[8] Bouchard R J, Russo P A. Inorganic Chemistry, 1965, 4(5):8.
[9] Xiao J W, Wan L, Yang S H, Wang S. Nano Letters, 2014, 14(2):831.
[10] Xia C, Li P, Gandi A N, Schwingenschl gl U, Alshareef H N. Chemistry of Materials, 2015, 27(19):6482.
[11] Wang J G, Jin D D, Zhou R, Shen C, Xie K Y, Wei B Q. Journal of Power Sources, 2016, 306:100.
[12] Zhang L S, Zuo L Z, Fan W, Liu T X. ChemElectroChem, 2016, 3(9):1384.
[13] Chen W, Xia C, Alshareef H N. ACS Nano, 2014, 8(9):9531.
[14] Wang M R, Lai Y Q, Fang J, Qin F R, Zhang Z, Li J, Zhang K. Catalysis Science & Technology, 2016, 6(2):434.
[15] Sivanantham A, Ganesan P, Shanmugam S. Advanced Functional Materials, 2016, 26(26):4661.
[16] Zhang Z Y, Wang X G, Cui G L, Zhang A H, Zhou X H, Xu H X, Gu L. Nanoscale, 2014, 6(7):3540.
[17] Liu Q, Jin J, Zhang J Y. ACS Applied Materials & Interfaces, 2013, 5(11):5002.
[18] Liu X B, Wu Z P. Materials Letters, 2016, 187:24.
[19] Chen J Z, Xu J L, Zhou S, Zhao N, Wong C P. Nano Energy, 2016, 25:193.
[20] Wang J G, Zhou R, Jin D D, Xie K Y, Wei B Q. Energy Storage Materials, 2015, 2:1.
[21] Zhou W W, Yu K, Wang D, Chu J, Li J Y, Zhao L M, Ding C Y, Du Y, Jia X T, Wang H T, Wen G W. Nanotechnology, 2016, 27(23):235402.
[22] Li Y H, Cao L J, Qiao L, Zhou M, Yang Y, Xiao P, Zhang Y H. Journal of Materials Chemistry A, 2014, 2(18):6540.
[23] Chen H C, Jiang J J, Zhang L, Xia D D, Zhao Y D, Guo D Q, Qi T, Wan H Z. Journal of Power Sources, 2014, 254(15):249.
[24] Pu J, Wang T T, Wang H Y, Tong Y, Lu C C, Kong W, Wang Z H. ChemPlusChem, 2014, 79(4):577.
[25] Yu D J, Yuan Y F, Zhang D, Yin S M, Lin J X, Rong Z, Yang J L, Chen Y B, Guo S Y. Electrochimica Acta, 2016, 198:280.
[26] Cai D P, Wang D D, Wang C X, Liu B, Wang L L, Liu Y, Li Q D,Wang T H. Electrochimica Acta, 2015, 151:35.
[27] Xiong X H, Waller G, Ding D, Chen D C, Rainwater B, Zhao B, Wang Z X, Liu M L. Nano Energy, 2015, 16:71.
[28] Chen H C, Chen S, Shao H Y, Li C, Fan M Q, Chen D, Tian G L, Shu K Y. Chemistry an Asian Journal, 2016, 11(2):248.
[29] Yang Y F, Cheng D, Chen S J, Guan Y L, Xiong J. Electrochimica Acta, 2016, 193:116.
[30] Wu Z B, Pu X L, Ji X B, Zhu Y R, Jing M J, Chen Q Y, Jiao F P. Electrochimica Acta, 2015, 174:238.
[31] Shen L F, Wang J, Xu G Y, Li H S, Dou H, Zhang X G. Advanced Energy Materials, 2015, 5(3):1400977.
[32] Peng T, Qian Z Y, Wang J, Song D L, Liu J Y, Liu Q, Wang P. Journal of Materials Chemistry A, 2014, 2(45):19376.
[33] Song Y, Chen Z L, Li Y M, Wang Q C, Fang F, Zhou Y N, Hu L F, Sun D L. Journal of Materials Chemistry A, 2017, 5:9022.
[34] Hou L R, Hua H, Bao R Q, Chen Z Y, Yang C, Zhu S Q, Pang G, Tong L N, Yuan C Z, Zhang X G. ChemPlusChem, 2016, 81(6):557.
[35] Jin R C, Liu G, Liu C P, Sun L L. Materials Research Bulletin, 2016, 80:309.
[36] Zou R J, Zhang Z Y, Yuen M F, Sun M L, Hu H Q, Lee C S, Zhang W J. NPG Asia Material, 2015, 7:e195.
[37] Lu F, Zhou M, Li W R, Weng Q H, Li C L, Xue Y M, Jiang X F, Zeng X H, Bando Y, Golberg D. Nano Energy, 2016, 26:313.
[38] Bai D X, Wang F, Lv J M, Zhang F Z, Xu S L. ACS Applied Materials & Interfaces, 2016, 8(48):32853.
[39] Zhang Y F, Ma M Z, Yang J, Sun C C, Su H Q, Huang W, Dong X C. Nanoscale, 2014, 6(16):9824.
[40] Chen H, Liu X L, Zhang J M, Dong F, Zhang Y X. Ceramics International, 2016, 42(7):8909.
[41] Li Z C, Ji X, Han J, Hu Y M, Guo R. Journal of Colloid & Interface Science, 2016, 477:46.
[42] Yang W W, Chen L A,Yang J, Zhang X, Fang C, Chen Z L, Huang L, Liu J G, Zhou Y, Zou Z G. Chemical Communications, 2016, 52(30):5258.
[43] Nguyen V H, Lamiel C, Shim J J. New Journal of Chemistry, 2016, 40(5):4810.
[44] Zhu Y R, Wu Z B, Jing M J, Yang X M, Song W X, Ji X B. Journal of Power Sources, 2015, 273:584.
[45] Zeng Z F, Wang D Z, Zhu J L, Xiao F Q, Li Y D, Zhu X H. CrystEngComm, 2016, 18(13):2363.
[46] Niu L Y, Wang Y D, Ruan F P, Shen C, Shan S, Xu M, Sun Z K, Li C, Liu X J, Gong Y Y. Journal of Materials Chemistry A, 2016, 4(15):5669.
[47] Wan H Z, Jiang J J, Yu J W, Xu K, Miao L, Zhang L, Chen H C, Ruan Y J. CrystEngComm, 2013, 15(38):7649.
[48] Pu J, Cui F L, Chu S B, Wang T T, Sheng E H, Wang Z H. ACS Sustainable Chemistry & Engineering, 2013, 2(4):809.
[49] Wen Y X, Peng S L, Wang Z L, Hao J X, Qin T F, Lu S Q, Zhang J C, He D Y, Fan X Y, Cao G Z. Journal of Materials Chemistry A, 2017, 5(15):7144.
[50] Li R, Wang S L, Huang Z C, Lu F X, He T B. Journal of Power Sources, 2016, 312:156.
[51] Hu C G, Zhai X Q, Liu L L, Zhao Y, Liang L, Qiu L T. Scientific Reports, 2013, 3(6):2065.
[52] Lee S K, Song M J, Kim J H, Kan T S, Lim Y K, Ahn J P, Lim D S. NPG Asia Materials, 2014, 6(7):e115.
[53] Zhang G Q, Xia B Y, Xiao C, Yu L, Wang X, Xie Y, Lou X W. Angewandte Chemie, 2013, 52(33):8643.
[54] Luo J S, Xia X H, Luo Y S, Guan C, Liu J L, Qi X Y, Ng C F, Yu T, Zhang H, Fan H J. Advanced Energy Materials, 2013, 3(6):737.
[55] Zhu P N, Wu Y Z, Reddy M V, Nair A S, Chowdari B V R, Ramakrishna S. RSC Advances, 2012, 2(2):531.
[56] Binitha G, Soumya M S, Madhavan A A, Praveen P, Subramanian K R V, Reddy M V, Nair S V, Nair A S, Sivakumar N. Journal of Materials Chemistry A, 2013, 1(38):11698.
[57] Li D L, Gong Y N, Pan C X. Scientific Reports, 2016, 6:29788.
[58] Li L J. Bifunctional Air Electrodes, 2014, 5:24936.
[59] Qian Y H, Hu Z G, Ge X M, Yang S L, Peng Y W, Kang Z X, Liu Z L, Lee J Y, Zhao D. Carbon, 2016, 111:641.
[60] Lyons M E G, Brandon M P. International Journal of Electrochemical Science, 2008, 3:1425.
[61] Chen P Z, Xu K, Fang Z W, Tong Y, Wu J C, Lu X L, Peng X, Ding H, Wu C Z, Xie Y. Angewandte Chemie, 2015, 54(49):14710.
[62] Jervis R, Mansor N, Gibbs C, Murray C A, Tang C U, Shearing P R, Brett D J L. Journal of the Electrochemical Society, 2014, 161(4):F458.
[63] Wu J B, Li Z G, Huang X H, Lin Y. Journal of Power Sources, 2013, 224(5):1.
[64] Chen D Y, Mei X, Ji G, Lu M H, Xie J P, Lu J M, Lee J Y. Angewandte Chemie, 2012, 51(10):2409.
[65] Chen Y J, Qu B H, Mei L, Lei D N, Chen L B, Li Q H, Wang T H. Journal of Materials Chemistry, 2012, 22(48):25373.
[66] Zhu J, Xu Z, Lu B G. Nano Energy, 2014, 7(7):114.
[67] Li J F, Xiong S L, Liu Y R, Ju Z C, Qian Y T. ACS Applied Materials & Interfaces, 2013, 5(3):981.
[68] Shen L F, Che Q, Li H S, Zhang X G. Advanced Functional Materials, 2014, 24(18):2630.
[69] Yamaguchi Y, Takeuchi T, Sakaebe H, Kageyama H, Seno H, Sakai T, Tatsumib K. Journal of the Electrochemical Society, 2010, 157(6):A630.
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