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Progress in Chemistry 2017, Vol. 29 Issue (10): 1273-1284 DOI: 10.7536/PC170403 Previous Articles   

• Review •

Strategies of Prior-Fractionation for the Graded Utilization of Lignocellulose

Yong Sun, Xiaoqiang Song, Yong Sun*, Xianhai Zeng, Xing Tang, Lu Lin*   

  1. College of Energy, Xiamen University, Xiamen 361102, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21676223, 21506177), the Fujian Provincial Development and Reform Commission, China (No. 2015489), the Fundamental Research Funds for the Central Universities (No. 20720160087, 20720160077, 20720170062), the Natural Science Foundation of Fujian Province of China (No. 2016J01077, 2015J05034), and the Education Department of Fujian Province (No. JZ160398).
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Lignocellulosic materials contributing the large proportion to the biomass resource are mainly composed of carbohydrate polymers (cellulose, hemicellulose), and aromatic macromolecules (lignin). Pre-fractionating lignocellulose is considered as the foundational step to establish an economical and sustainable lignocellulosic biorefinery. Firstly, the distinction between lignocellulose fractionation technologies and pretreatment methods for cellulosic ethanol production is discussed. Afterwards, five prior-fractionating strategies of lignocellulose for the biorefinery process are elaborated, including cellulose-first processing, lignin-first processing, hemicellulose-first processing, lignin & hemicellulose-first processing, and cellulose & hemicellulose-first processing. And then industrial applications of hemicellulose-first processing in our country are reviewed. Ultimately, the future perspective on lignocellulose fractionation technologies are given. The aim of this review is to provide new insights into the lignocellulosic biorefinery based on the fractionating of lignocellulose.
Contents
1 Introduction
2 The similarity and difference between lignocellulose pretreatment and fractionation
3 Prior-fractionating strategies of lignocellulose for biorefinery
3.1 Cellulose-first processing
3.2 Lignin-first processing
3.3 Hemicellulose-first processing
3.4 Lignin&hemicellulose-first processing
3.5 Cellulose&hemicellulose-first processing
4 Industrial cases of hemicellulose-first strategy
4.1 Co-production of dissolving pulp and xylitol/furfural
4.2 Co-production of citric acid and xylitol/arabinose
4.3 Co-production of xylooligosaccharide and lignocellulosic ethanol
4.4 Co-production of furfural and ethanol
4.5 Co-production of vehicle fuels and chemicals
5 Conclusion
Key words: biorefinery, biomass, lignocellulose, fractionation, pretreatment

CLC Number: 

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