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Progress in Chemistry 2017, Vol. 29 Issue (7): 695-705 DOI: 10.7536/PC170347 Previous Articles   Next Articles

• Review •

CO2-Responsive Emulsion Systems

Shuang Guo, Zhiqiang Chen, Xiaofei Ren, Yongmin Zhang*, Xuefeng Liu*   

  1. Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No.21503094)
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Emulsions play an important role in a number of industrial processes and commercial products where immiscible liquid phases coexist. Recently how to balance the long-term stability and quick demulsification has become a key focus in emulsions. The emergence of stimuli-responsive emulsions has brought a ray of dawn. Over the past decade, CO2 as alternative of pH has aroused considerable attention in the fields of surfactants and their aggregates, polymers, solvents, as well as microemulsions, because of its renewability, low cost and good biocompatibility. Essentially CO2 acts as pH, but the former offers more advantages over the latter. However, the focus until recently shifted to the utilization of CO2 as a trigger for triggering emulsions between "on" (stable) or "off" (unstable) states. These CO2-responsive emulsions show considerable application potential in oil recovery, emulsion polymerization, extraction separation, cosmetics and other fields, because they can smartly response to the removal or bubbling of CO2 gas, reflecting in emulsification or demulsification of oil/water mixture. In this review, we highlight the recent advances in this field from general emulsion, Pickering emulsion, and microemulsion, respectively. The principle, performance and applications of the CO2-responsive emulsion system are introduced in details, and their future development and perspectives are also outlooked.
Contents
1 Introduction
2 CO2-responsive emulsions/microemulsions
2.1 CO2-responsive general emulsions
2.2 CO2-responsive Pickering emulsions
2.3 CO2-responsive microemulsions
3 Conclusion
Key words: CO2-responsive, microemulsion, Pickering emulsion

CLC Number: 

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Abstract

CO2-Responsive Emulsion Systems