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Progress in Chemistry 2017, Vol. 29 Issue (1): 7-8 DOI: 10.7536/PC170103 Previous Articles   Next Articles

Special Issue: 中国化学印记; 金属有机框架材料

• Imprint of Chinese Chemistry •

Sandwich MOFs as Catalyst: Regulating Selectivity for Hydrogenation

Minghua Liu*   

  1. National Center for Nanoscience and Technology, Beijing 100190, China
  • Online: Published:
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This 2016 Chinese Chemistry Engram highlights the MOF catalyst for selective hydrogenation. The MOF catalyst is fabricated by sandwiching platinum nanoparticles between an inner core and an outer shell of an MOF with metal nodes of Fe3+, Cr3+ or both (known as MIL-101), which can convert a range of α, β-unsaturated aldehydes with high efficiency and with significantly enhanced selectivity towards unsaturated alcohols.
[1] Yaghi O M, Li G, Li H. Nature, 1995, 378:703.
[2] Zhao M, Yuan K, Wang Y, Li G, Guo J, Gu L, Hu W, Zhao H, Tang Z. Nature, 2016, 539:76.
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