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Progress in Chemistry 2017, Vol. 29 Issue (4): 426-434 DOI: 10.7536/PC161234 Previous Articles   Next Articles

• Review •

Synthesis and Dehydrogenation of Hydrazine Borane

Shiliang Zhang, Qilu Yao, Zhanghui Lu*   

  1. Jiangxi Inorganic Membrane Materials Engineering Research Centre, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21463012, 21103074)and the Natural Science Foundation of Jiangxi Province of China (No. 2016BAB203087).
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Hydrazine borane (N2H4BH3, HB) is considered as a highly promising hydrogen storage material due to its high hydrogen content (15.4 wt%), easy preparation, and good physical and chemical properties. Hydrogen can be produced from hydrazine borane via pyrolysis, methanolysis and hydrolysis reaction. Especially, a promising approach for complete hydrogen production from N2H4BH3 is by hydrolysis of the BH3 group and selective decomposition of the N2H4 moiety of N2H4BH3, corresponding to a theoretical gravimetric hydrogen storage capacity (GHSC) of 10 wt% for the system N2H4BH3-3H2O. The GHSC of N2H4BH3 is much higher than those of benchmark hydrogen storage systems NaBH4-4H2O (7.3 wt%), NH3BH3-4H2O (5.9 wt%), and N2H4·H2O (8.0 wt%). The suitable catalyst is essential for complete hydrogen generation from N2H4BH3. In this paper, the synthesis and characterizations of hydrazine borane are briefly introduced. The developments of catalytic systems for hydrogen production from hydrolysis of the BH3 group and dehydrogenation of the N2H4 moiety of hydrazine borane at mild conditions are significantly reviewed. Moreover, the mechanism of hydrogen production from hydrazine borane is concisely analyzed and the application prospects of hydrazine borane are also remarked in this review.

Contents
1 Introduction
2 Synthesis and characterization of hydrazine borane
2.1 Synthesis
2.2 Molecular and structural analyses
3 Dehydrogenation of hydrazine borane
3.1 Hydrolysis of the BH3 group of hydrazine borane
3.2 Hydrolysis of the BH3 group and dehydrogenation of the N2H4 moiety of hydrazine borane
3.3 Reaction mechanism of complete dehydrogenation of hydrazine borane
4 Conclusion

Key words: chemical hydrogen storage material, hydrazine borane, hydrogen production, catalyst

CLC Number: 

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