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Progress in Chemistry 2017, Vol. 29 Issue (5): 563-578 DOI: 10.7536/PC161202 Previous Articles   

• Review •

Transformation of Lignin and Its Model Compounds into Value-Added Chemicals Using Sulfide Catalysts

Na Ji1,2, Jingjing Song1,2, Xinyong Diao1,2, Chunfeng Song1,2, Qingling Liu1,2, Mingyuan Zheng3   

  1. 1. School of Environmental Science and Engineering, Tianjin University, Tianjin 300350, China;
    2. Key Laboratory of Biomass-Derived Gas and Oil for Chinese Petrochemical Industry, Tianjin 300350, China;
    3. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No.21503144,21406165,51506147,21376239),the Major Projects of the National Natural Science Foundation of China (No.21690083),and the Tianjin Research Program of Application Foundation and Advanced Technique (No.16JCQNJC05400,15JCQNJC08500).
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Lignin is mainly composed of hydroxy-substituted or methoxylated phenyl propane structures and serves as the only renewable bulk feedstock in nature for producing aromatic chemicals. By using suitable catalysts, the long chain structures of lignin can be selectively broken down to obtain different target products. This has been regarded as an important approach for the comprehensive utilization of lignin. Due to the high activity of hydrodeoxygenation, transition metal sulfide catalysts have been used in lignin conversion in recent decades. In this review, the application of transition metal sulfide catalysts in the catalytic conversions of lignin and its model compounds are summarized. The active components, support materials, reaction conditions and reaction mechanism are presented in detail. The existing challenges of sulfide catalysts in the degradation of lignin are discussed. Finally, potential solutions and future trends of this field are presented.
Contents
1 Introduction
2 The application of sulfide catalysts in the hydrodeoxygenation of lignin model compounds
2.1 Mo-based sulfide catalyst
2.2 Other sulfide catalysts
3 The application of sulfide catalysts in the degradation of lignin raw materials
4 Conclusion
Key words: lignin, sulfide, aromatic compound, hydrodeoxygenation, catalytic degradation

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