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Progress in Chemistry 2017, Vol. 29 Issue (2/3): 241-251 DOI: 10.7536/PC161023 Previous Articles   Next Articles

• Review •

Preparation of Graphite Phase C3N4 and Bismuth Based Composite Photocatalyst and Its Environmental Application

Pengyuan Wang1,2, Changsheng Guo2*, Jianfeng Gao1, Jian Xu2   

  1. 1. School of Science, North University of China, Taiyuan 030051, China;
    2. State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China
  • Received: Revised: Online: Published:
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Semiconductor photocatalytic technology has been proved as an effective way to solve the problems of both environmental pollution and energy shortage. It can be applied for the degradation, transformation and mineralization of pollutants in the environment, and for the conversion of solar energy as well. Graphite phase carbon nitride (g-C3N4) and bismuth based composite materials have become the hot research topic because of their excellent photocatalytic performance. This paper reviews the preparation methods of g-C3N4 and its composites with different bismuth compounds. We also reviews the recent advances of the application of g-C3N4 and Bi composites in the environmental purification, including the elimination of pollutants in water, the light induced bacterial inactivation, and the photoinduced hydrolysis for hydrogen production. Taking the elimination of organic contaminants in water as an example, this paper elaborate detailedly their mechanisms of photocatalytic degradation. Finally, we prospect the new development and application potential of the g-C3N4 and Bi based composite photocatalytic materials in the environmental field.

Contents
1 Introduction
2 Synthesis of g-C3N4
2.1 Thermal polymerization method
2.2 Solvothermal synthesis
2.3 Electrochemical deposition
2.4 Solid phase synthesis
3 Preparation of g-C3N4 and bismuth based composites
3.1 Preparation of g-C3N4/Bi based halide oxides composites
3.2 Preparation of g-C3N4 and bismuth metal salts composites
3.3 Preparation of g-C3N4 and other bismuth compounds
4 Application of composites in the environment
4.1 Removal of organic pollutants in water environment
4.2 Photocatalytic hydrogen production by water splitting
4.3 Application of composite materials in other areas
5 Reaction mechanisms
6 Conclusion

Key words: photocatalysis, g-C3N4, bismuth based composites, catalytic application, mechanism

CLC Number: 

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