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Progress in Chemistry 2017, Vol. 29 Issue (2/3): 231-240 DOI: 10.7536/PC161012 Previous Articles   Next Articles

• Review •

Adsorption Materials for Lithium Ion from Brine Resources and Their Performances

Wen Zhang1*, Yingxin Mou1, Song Zhao1, Lixin Xie1, Yuxin Wang1, Jing Chen2   

  1. 1. Key Laboratory of Membrane Science & Desalination Technology, State Key Laboratory of Chemical Engineering, School of Chemical Engineering, Tianjin University, Tianjin 300350, China;
    2. Institute of Nuclear and New Energy Technology, Collaborative Innovation Center of Advanced Nuclear Technology, Tsinghua University, Beijing 102201, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No.U1430234), the Science and Technology Program of Tianjin (No.16JCQNJC06000) and the National Key Technology Support Program(No. 2015BAB10B00).
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Lithium is a very important metal resource for lithium-ion batteries and nuclear industries. With the fast-growing market demand for lithium, the focus of lithium extraction technologies has shifted to aqueous lithium resources, such as seawater and salt lake brine. Adsorption method has been recognized as one of the most suitable technologies for recovery of lithium from aqueous resources. The present paper reviews the development of the adsorption materials of lithium ion comprehensively, including the inorganic adsorbents (the natural ores, carbon materials, Mn or Ti lithium ion-sieves and their forming techniques) and organic composite adsorbents. The organic ligand functional groups (crown ether, calixarene and phosphate) for lithium ion adsorption, and their bonded matrixs are also summarized. The adsorption mechanism, adsorption capacity and selectivity of dififferent adsorption materials are compared. This paper provides a reference for developing of novel adsorption materials and separation systems to extract lithium ion from aqueous brine resources.

Contents
1 Introduction
2 Inorganic materials for adsorption of lithium
2.1 Natural ores and carbon materials
2.2 Lithium ion sieves
2.3 Lithium ion sieves composite materials
3 Composite materials for adsorption of lithium
3.1 Organo-functional groups of composite materials
3.2 Matrixes of composite materials
3.3 Composite materials with lithium ion imprinting technology
4 Conclusion

Key words: seawater, salt lake brine, extraction of lithium, adsorption materials

CLC Number: 

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