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Progress in Chemistry 2016, Vol. 28 Issue (12): 1860-1869 DOI: 10.7536/PC160731 Previous Articles   Next Articles

• Review and comments •

Selective Catalytic Reduction of NOx from Diesel Engine with NH3 over Zeolites Catalysts with Chabazite

Xie Lijuan1,2, Shi Xiaoyan3,4, Liu Fudong3,4, Ruan Wenquan1,2*   

  1. 1. School of Environment and Civil Engineering, Jiangnan University, Wuxi 214122;
    2. Jiangsu Key Laboratory of Anaerobic Biotechnology, Wuxi 214122, China;
    3. Research Center for Eco-environmental Science, Chinese Academy of Sciences, Beijing 100085, China;
    4. University of Chinese Academy of Sciences, Beijing 100049, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No.51508231, 51278486) and the Fundamental Research Funds for the Central Universities (JUSRP11524).
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The purification of NOx from diesel engine exhaust is an important topic in the field of air pollution control, which is significant for the improvement of current unban air quality. The selective catalytic reduction of NOx with NH3 (NH3-SCR) is one of the most promising technologies for the control of NOx emission from diesel engine exhaust. In recent years, Cu-CHA catalysts, which are obtained from loading transition metal Cu on zeolites with chabazite (CHA) structure, have attracted much attention in the field of NH3-SCR reaction, due to their excellent NH3-SCR activity and hydrothermal stability. Cu-SSZ-13 and Cu-SAPO-34 are the two typical Cu-CHA catalysts. In this review, the progress of NOx control in the field of diesel engine exhaust with Cu-CHA catalysts is stated from three aspects firstly, including the influences of preparation method, the effects of reaction condition and the NH3-SCR reaction mechanism. Then, the application of M-CHA catalysts in NH3-SCR reaction are elaborated, where M is limited as some other transition metal and rare earth metal. Meanwhile, the advantages of bimetallic-based CHA zeolites in NH3-SCR reaction are identified. Based on these results, the possible improvement orientations for NH3-SCR catalysts with CHA zeolites structure are also prospected.

Contents
1 Introduction
2 Application of Cu-CHA catalysts in NH3-SCR
2.1 Cu-SSZ-13 used for NOx purification
2.2 Cu-SAPO-34 used for NOx purification
3 Application of Fe-CHA catalysts in NH3-SCR
4 Application of bimetallic active center catalysts with CHA structure in NH3-SCR
5 Conclusion and outlook

Key words: NOx control, selective catalytic reduction of NH3, chabazite, reaction mechanism, bimetallic active center

CLC Number: 

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