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Progress in Chemistry 2016, Vol. 28 Issue (8): 1186-1195 DOI: 10.7536/PC160342 Previous Articles   Next Articles

• Review and comments •

Preparation and Surface-Enhanced Raman Scattering Effect of Graphene Oxide/(Au/Ag) Hybrid Materials

Hao Rui1,2, Zhang Congyun1,2*, Lu Ya1,2, Zhang Dongjie1,2, Hao Yaowu3, Liu Yaqing1,2   

  1. 1. Shanxi Province Key Laboratory of Functional Nanocomposites, North University of China, Taiyuan 030051, China;
    2. School of Materials Science and Engineering, North University of China, Taiyuan 030051, China;
    3. Department of Materials Science and Engineering, The University of Texas at Arlington, Arlington 76019, USA
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the International Science and Technology Program of Shanxi Province (No.2014081006-2), and the Natural Science Foundation for Young Scientists of Shanxi Province, China(No.2015021078)
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Graphene oxide/(Au/Ag) hybrid materials, which have significant value in pollutant detection, chemical sensing and cancer diagnosis, have received considerable attention for recent years because of their excellent surface-enhanced Raman scattering (SERS) effects. In this review, the synthesis methods and SERS effects of three kind of graphene oxide/(Au/Ag) hybrid materials (graphene oxide decorated with Au/Ag nanoparticles, graphene oxide encapsulated Au/Ag nanoparticles, graphene oxide coated on Au/Ag nanoparticles films) have been summarized in detail. SERS studies show that by combining with the respective advantages of Au/Ag nanoparticles and graphene oxide on the research and application of SERS, graphene oxide/(Au/Ag) hybrid materials have more excellent SERS effect than pure Au/Ag nanoparticles. Graphene oxide plays an important role in chemical enhancement, molecule enrichment, surface passivation and fluorescence quencher. Graphene oxide/(Au/Ag) hybrid materials have broad application prospects in SERS.

Contents
1 Introduction
2 Preparation of graphene oxide/(Au/Ag) hybrid materials
2.1 Graphene oxide decorated with Au/Ag nanoparticles
2.2 Graphene oxide encapsulated Au/Ag nanoparticles
2.3 Graphene oxide coated on Au/Ag nanoparticles films
3 SERS effect of graphene oxide/(Au/Ag) hybrid materials
3.1 SERS effect of different structure of graphene oxide/(Au/Ag) hybrid materials
3.2 The practical SERS application of graphene oxide/(Au/Ag) hybrid materials
4 Conclusion

Key words: Au and Ag nanoparticles, graphene oxide, hybrid materials, surface-enhanced Raman scattering (SERS)

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