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Progress in Chemistry 2016, Vol. 28 Issue (8): 1156-1169 DOI: 10.7536/PC160312 Previous Articles   Next Articles

• Review and comments •

Functionalized Iron-Based Nano-Materials for Removal of Mercury from Aqueous Solution

Sun Yue, Zhou Xiaoxin, Lou Zimo, Liu Yu, Fu Ruiqi, Xu Xinhua*   

  1. Department of Environmental Engineering, Zhejiang University, Hangzhou 310058, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21477108, 21277119)
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Mercury pollution has posed increasingly severe threat to environment all over the world. Dealing with the problem of mercury contamination in water bodies is extremely urgent. The iron-based nanoparticles like FeSx、Fe3O4、Fe are used to remove mercury from aqueous solutions due to their high adsorption capacity and large surface area. In addition, using particle stabilization techniques and functional group modification could increase the dispersion of iron-based nanoparticles, offer more adsorption sites for the adsorption of mercury, which could enhance the effect of mercury removal. This paper emphasizes on the stabilization of FeSx nanoparticles, thiol-functionalization and amino-functionalization of Fe3O4, etc. The applications of functionalized iron-based nano-materials are summarized. The influential factors of mercury removal by iron-based materials are further discussed, and then the adsorption mechanisms of mercury by functionalized iron-based nanoparticles are also explored. Finally, the outlook of mercury removal in water environment by modified iron-based nano-materials are presented.

Contents
1 Introduction
2 Functional iron sulfide
2.1 Bio-stabilizer stabilized iron sulfide
2.2 Supported iron sulfide
2.3 The mechanisms of mercury removal by iron sulfide
3 Functional magnetic iron-based materials
3.1 Thiol-functionalization
3.2 Amino-functionalization
3.3 Other functionalizations
3.4 The mechanisms of mercury removal by magnetic iron-based materials
4 Other iron-based materials
5 Conclusion

Key words: iron-based nano-materials, functionalization, mercury removal

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