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Progress in Chemistry 2016, Vol. 28 Issue (7): 1016-1028 DOI: 10.7536/PC160201 Previous Articles   Next Articles

• Review and comments •

Metal Organic Frameworks for Bi- and Multi-Metallic Catalyst and Their Applications

Qiu Jianhao1, He Ming2, Jia Mingmin1, Yao Jianfeng1*   

  1. 1. College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China;
    2. College of Science, Nanjing Forestry University, Nanjing 210037, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the Natural Science Key Project of Jiangsu Higher Education Institutions (No.15KJA220001).
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Metal organic frameworks (MOFs) are very popular materials and have been largely researched in recent years. They have extremely wide ranges of applications in catalysis because of their variety of excellent properties. However, the research of MOFs themselves as catalysts is limited, the regularly porous structure and large surface area of MOFs can provide a natural physical space for loading highly dispersed metal nanocatalyst, which prevents the aggregation and leaching of metal nanoparticals. This has also been the major research direction of MOF catalysts in the last few years. This review reports the preparation methods of loading metal nanoparticles on MOFs to form bi- and multi-metallic catalysts and their applications in catalysis. The preparation methods,such as one pot synthesis, adsorption-reduction method, metal organic chemical vapor deposition method and solid grinding method are highlighted, and their applications in oxidation (the oxidation of alcohols, alkanes, alkenes and CO), hydrogenation (the hydrogenation of carbonyl compounds and olefinic compounds), Knoevenagel condensation and photocatalytic reaction (photocatalytic degradation of organic compounds and light-driven water splitting to produce hydrogen) are discussed in detail. In addition,the existing problems and the development prospects of such bi- and multi-metallic catalysts are also addressed in this review.

Contents
1 Introduction
2 The preparation methods of bi- or multi-metallic catalyst
2.1 One pot synthesis
2.2 Adsorption-reduction method
2.3 Metal organic chemical vapor deposition
2.4 Solid Grinding
2.5 Other methods
3 The applications of bimetallic or multi-metal catalyst
3.1 Oxidation reaction
3.2 Hydrogenation reaction
3.3 Knoevenagel condensation
3.4 Photocatalytic reaction
4 Conclusion and outlook

Key words: metal organic framework, metal nanoparticles, bimetallic or multi-metal catalyst, preparation, catalytic reaction

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[1] James S L. Chem. Soc. Rev., 2003, 32:276.
[2] Janiak C. Dalton Trans., 2003:2781.
[3] Rowsell J L C, Yaghi O M. Microporous Mesoporous Mater., 2004, 73:3.
[4] Ferey G. Chem. Soc. Rev., 2008, 37:191.
[5] Millward A R, Yaghi O M. J. Am. Chem. Soc., 2005, 127:17998.
[6] Yazaydin A O, Snurr R Q, Park T H, Koh K, Liu J, LeVan M D, Benin A I, Jakubczak P, Lanuza M, Galloway D B, Low J J, Willis R R. J. Am. Chem. Soc., 2009, 131:18198.
[7] Yao J F, Wang H T. Chem. Soc. Rev., 2014, 43:4470.
[8] Yao J F, Dong D H, Li D, He L, Xu G S, Wang H T. Chem. Commun., 2011, 47:2559.
[9] He M, Yao J F, Low Z X, Yu D B, Feng Y, Wang H T. RSC Adv., 2014, 4:7634.
[10] Xu G S, Yao J F, Wang K, He L, Webley P A, Chen C S, Wang H T. J. Membr. Sci., 2011, 385:187.
[11] Corma A, Garcia H, Xamena F X L I. Chem. Rev., 2010, 110:4606.
[12] Farrusseng D, Aguado S, Pinel C. Angew. Chem. Int. Ed., 2009, 48:7502.
[13] Dhakshinamoorthy A, Garcia H. Chem. Soc. Rev., 2012, 41:5262.
[14] Horcajada P, Chalati T, Serre C, Gillet B, Sebrie C, Baati T, Eubank J F, Heurtaux D, Clayette P, Kreuz C, Chang J S, Hwang Y K, Marsaud V, Bories P-N, Cynober L, Gil S, Ferey G, Couvreur P, Gref R. Nat. Mater., 2010, 9:172.
[15] Kreno L E, Leong K, Farha O K, Allendorf M, Van Duyne R P, Hupp J T. Chem. Rev., 2012, 112:1105.
[16] Lu Z Z, Zhang R, Li Y Z, Guo Z J, Zheng H G. J. Am. Chem. Soc., 2011, 133:4172.
[17] 张慧(Zhang H), 周雅静(Zhou Y J), 宋肖锴(Song X K). 化学进展(Progress in Chemistry), 2015, 2:174.
[18] Liu Q, Low Z X, Li L X, Razmjou A, Wang K, Yao J F, Wang H T. J. Mater. Chem. A, 2013, 1:11563.
[19] Liu Q, Low Z X, Feng Y, Leong S, Zhong Z X, Yao J F, Hapgood K, Wang H T. Microporous Mesoporous Mater., 2014, 194:1.
[20] Yao J F, He M, Wang K, Chen R Z, Zhong Z X, Wang H T. Crystengcomm, 2013, 15:3601.
[21] He M, Yao J F, Liu Q, Zhong Z X, Wang H T. Dalton Trans., 2013, 42:16608.
[22] Fujita M, Kwon Y J, Washizu S, and Ogura K. J. Am. Chem. Soc., 1994, 116:1151.
[23] Lee J, Farha O K, Roberts J, Scheidt K A, Nguyen S T, Hupp J T. Chem. Soc. Rev., 2009, 38:1450.
[24] Gao J, Miao J, Li P Z, Teng W Y, Yang L, Zhao Y, Liu B, Zhang Q. Chem. Commun., 2014, 50:3786.
[25] Junghans U, Suttkus C, Lincke J, Laessig D, Krautscheid H, Glaeser R. Microporous Mesoporous Mater., 2015, 216:151.
[26] Seo J S, Whang D, Lee H, Jun S I, Oh J, Jeon Y J, Kim K. Nature, 2000, 404:982.
[27] Hasegawa S, Horike S, Matsuda R, Furukawa S, Mochizuki K, Kinoshita Y, Kitagawa S. J. Am. Chem. Soc., 2007, 129:2607.
[28] Meilikhov M, Yusenko K, Esken D, Turner S, van Tendeloo G, Fischer R A. Eur. J. Inorg. Chem., 2010:3701.
[29] Arnanz A, Pintado-Sierra M, Corma A, Iglesias M, Sanchez F. Adv. Synth. Catal., 2012, 354:1347.
[30] Bhattacharjee S, Lee Y R, Puthiaraj P, Cho S M, Ahn W S. Catal. Surv. Asia, 2015, 19:203.
[31] Ferey G, Mellot-Draznieks C, Serre C, Millange F, Dutour J, Surble S, Margiolaki I. Science, 2005, 309:2040.
[32] Kim J, Cho H Y, Ahn W S. Catal. Surv. Asia, 2012, 16:106.
[33] D'Souza D M, Mueller T J J. Chem. Soc. Rev., 2007, 36:1095.
[34] Sankar M, Dimitratos N, Miedziak P J, Wells P P, Kiely C J, Hutchings G J. Chem. Soc. Rev., 2012, 41:8099.
[35] Yu X, Cohen S M. Chem. Commun., 2015, 51:9880.
[36] Huang Y, Zhang Y, Chen X, Wu D, Yi Z, Cao R. Chem. Commun., 2014, 50:10115.
[37] 魏文英(Wei W Y),方键(Fang J),孔海宁(Kong H N),韩金玉(Han J Y),常贺英(Chang H Y). 化学进展(Progress in Chemistry). 2005, 17:1110.
[38] Juan-Alcaniz J, Ramos-Fernandez E V, Lafont U, Gascon J, Kapteijn F. J. Catal., 2010, 269:229.
[39] Yang X L, Qiao L M, Dai W L. Microporous Mesoporous Mater., 2015, 211:73.
[40] Roesler C, Esken D, Wiktor C, Kobayashi H, Yamamoto T, Matsumura S, Kitagawa H, Fischer R A. Eur. J. Inorg. Chem., 2014:5514.
[41] Liu H, Liu Y, Li Y, Tang Z, Jiang H. J. Phys. Chem. C, 2010, 114:13362.
[42] Chen L, Chen H, Li Y. Chem. Commun., 2014, 50:14752.
[43] Liu H, Chang L, Chen L, Li Y. J. Mater. Chem. A, 2015, 3:8028.
[44] Pastoriza-Santos I, Liz-Marzan L M. Adv. Funct. Mater., 2009, 19:679.
[45] Aguirre M E, Rodriguez H B, San Roman E, Feldhoff A, Grela M A. J. Phys. Chem. C, 2011, 115:24967.
[46] Yamamoto H, Yano H, Kouchi H, Obora Y, Arakawa R, Kawasaki H. Nanoscale, 2012, 4:4148.
[47] Shen L J, Wu W M, Liang R W, Lin R, Wu L. Nanoscale, 2013, 5:9374.
[48] Sabo M, Henschel A, Froede H, Klemm E, Kaskel S. J. Mater. Chem., 2007, 17:3827.
[49] Henschel A, Gedrich K, Kraehnert R, Kaskel S. Chem. Commun., 2008:4192.
[50] Choi K M, Na K, Somorjai G A, Yaghi O M. J. Am. Chem. Soc., 2015, 137:7810.
[51] Pan Y, Yuan B, Li Y, He D. Chem. Commun., 2010, 46:2280.
[52] Puthiaraj P, Ahn W S. Catal. Commun., 2015, 65:91.
[53] Qi Y, Luan Y, Peng X, Yang M, Hou J, Wang G. Eur. J. Inorg. Chem., 2015:5099.
[54] Zhu Q L, Li J, Xu Q. J. Am. Chem. Soc., 2013, 135:10210.
[55] Bhattacharjee S, Kim J, Ahn W-S. J. Nanosci. Nanotechnol., 2014, 14:2546.
[56] Yiping Zhang Z Y, and Richard J. Puddephatt. Chem. Mater., 1998, 10:2293.
[57] David B. Beach F K L, and, Hu C-K. Chem. Mater., 1990, 2:216.
[58] Mueller M, Hermes S, Kaehler K, van den Berg M W E, Muhler M, Fischer R A. Chem. Mater., 2008, 20:4576.
[59] Okumura M, Tsubota S, Haruta M. J. Mol. Catal. A, 2003, 199:73.
[60] Hermes S, Schroter M K, Schmid R, Khodeir L, Muhler M, Tissler A, Fischer R W, Fischer R A. Angew. Chem. Int. Ed., 2005, 44:6237.
[61] Hermes S, Schroder F, Amirjalayer S, Schmid R, Fischer R A. J. Mater. Chem., 2006, 16:2464.
[62] Esken D, Turner S, Lebedev O I, Van Tendeloo G, Fischer R A. Chem. Mater., 2010, 22:6393.
[63] Hermannsdoerfer J, Friedrich M, Miyajima N, Albuquerque R Q, Kuemmel S, Kempe R. Angew. Chem. Int. Ed., 2012, 51:11473.
[64] Luz I, Rosler C, Epp K, Xamena F, Fischer R A. Eur. J. Inorg. Chem., 2015:3904.
[65] Ishida T, Nagaoka M, Akita T, Haruta M. Chem. Eur. J., 2008, 14:8456.
[66] Jiang H L, Liu B, Akita T, Haruta M, Sakurai H, Xu Q. J. Am. Chem. Soc., 2009, 131:11302.
[67] El-Shall M S, Abdelsayed V, Khder A E R S, Hassan H M A, El-Kaderi H M, Reich T E. J. Mater. Chem., 2009, 19:7625.
[68] Martis M, Mori K, Fujiwara K, Ahn W-S, Yamashita H. J. Phys. Chem. C, 2013, 117:22805.
[69] Hou J, Luan Y, Tang J, Wensley A M, Yang M, Lu Y. J. Mol. Catal. A:Chem., 2015, 407:53.
[70] Liu H, Li Y, Jiang H, Vargas C, Luque R. Chem. Commun., 2012, 48:8431.
[71] Long J, Liu H, Wu S, Liao S, Li Y. ACS Catal., 2013, 3:647.
[72] Maksimchuk N V, Timofeeva M N, Melgunov M S, Shmakov A N, Chesalov Y A, Dybtsev D N, Fedin V P, Kholdeeva O A. J. Catal., 2008, 257:315.
[73] 谭海燕(Tan H Y), 吴金平(Wu J P). 物理化学学报(Acta Phys. -Chim. Sin.),2014, 30:715.
[74] Opelt S, Tuerk S, Dietzsch E, Henschel A, Kaskel S, Klemm E. Catal. Commun., 2008, 9:1286.
[75] Wan Y, Chen C, Xiao W, Jian L, Zhang N. Microporous Mesoporous Mater., 2013, 171:9.
[76] Hongli Liu R F, Zhong Li, Yingwei Li. Chem. Eng. Sci., 2015, 122:350.
[77] Wang C, Zhang H, Feng C, Gao S, Shang N, Wang Z. Catal. Commun., 2015, 72:29.
[78] Faustini M, Kim J, Jeong G Y, Kim J Y, Moon H R, Ahn W S, Kim D P. J. Am. Chem. Soc., 2013, 135:14619.
[79] Abdelhameed R M, Simoes M M Q, Silva A M S, Rocha J. Chem. Eur. J., 2015, 21:11072.
[80] Sha Z, Wu J. RSC Adv., 2015, 5:39592.
[81] He J, Wang J Q, Chen Y J, Zhang J P, Duan D L, Wang Y, Yan Z Y. Chem. Commun., 2014, 50:7063.
[82] Pascanu V, Yao Q, Gomez A B, Gustafsson M, Yun Y, Wan W, Samain L, Zou X, Martin-Matute B. Chem. Eur. J., 2013, 19:17483.
[83] Carson F, Pascanu V, Gomez A B, Zhang Y, Platero-Prats A E, Zou X D, Martin-Matute B. Chem. Eur. J., 2015, 21:10896.
[84] Kim S N, Yang S T, Kim J, Park J E, Ahn W S. Crystengcomm, 2012, 14:4142.
[85] Dai H, Xia B, Wen L, Du C, Su J, Luo W, Cheng G. Appl.Catal. B-Environ., 2015, 165:57.
[86] 郝志谋(Hao Z M), 李季(Li J). 化学进展(Progress in Chemistry), 2012, 24:1506.
[87] Shilov A E, Shul'pin G B. Chem. Rev., 1997, 97:2879.
[88] Kesavan L, Tiruvalam R, Ab Rahim M H, bin Saiman M I, Enache D I, Jenkins R L, Dimitratos N, Lopez-Sanchez J A, Taylor S H, Knight D W, Kiely C J, Hutchings G J. Science, 2011, 331:195.
[89] Schroeder F, Henke S, Zhang X, Fischer R A. Eur. J. Inorg. Chem., 2009:3131.
[90] Li H L, Eddaoudi M, O'Keeffe M, Yaghi O M. Nature, 1999, 402:276.
[91] 童敏曼(Tong M M),赵旭东(Zhao X D),解丽婷(Xie L T),刘大欢(Liu D H),阳庆元(Yang Q Y),仲崇立(Zhong C L). 化学进展(Progress in Chemistry), 2012, 24:1646.
[92] Hashimoto K, Irie H, Fujishima A. Japanese Journal of Applied Physics Part 1-Regular Papers Brief Communications & Review Papers, 2005, 44:8269.
[93] Lu H Q, Zhao B B, Zhang D, Lv Y L, Shi B P, Shi X C, Wen J, Yao J F, Zhu Z P. J. Photochem. Photobiol. A-Chem., 2013, 272:1.
[94] Lu H Q, Zhao B B, Pan R L, Yao J F, Qiu J H, Luo L, Liu Y C. RSC Adv., 2014, 4:1128.
[95] Li H, Hao Y, Lu H, Liang L, Wang Y, Qiu J, Shi X, Wang Y, Yao J. Appl. Surf. Sci., 2015, 344:112.
[96] Wang Y, Lu H, Wang Y, Qiu J, Wen J, Zhou K, Chen L, Song G, Yao J. RSC Adv., 2016, 6:1860.
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