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Progress in Chemistry 2016, Vol. 28 Issue (6): 801-813 DOI: 10.7536/PC160102 Previous Articles   Next Articles

• Review and comments •

Catalytic Asymmetric Syntheses of Indenes and Their Derivatives

He Qiao2, Yin Zhongqiong3, Chen Huabao2, Zhang Zumin1, Wang Xianxiang1, Yue Guizhou1,2*   

  1. 1. College of Science, Sichuan Agricultural University, Ya'an 625014, China;
    2. College of Agricultural Sciences, Sichuan Agricultural University, Chengdu 611130, China;
    3. College of Veterinary Medicine, Sichuan Agricultural University, Chengdu 611130, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the Science & Technology Department of Sichuan Province (No. 2012JY0118) and the "dual support" Project of Sichuan Agricultural University.
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Indenes and their derivatives widely exists in natural world, and some of them bearing multi-functional groups are very potential to become the lead compounds in drug because of their important bioactivities. In particular, asymmetric syntheses of indenes have attracted the extensive attention of organic chemists. Recently, many synthetic methods of them have been reported, including resolution of racemic mixture, syntheses of chiral auxiliary or substrate's induction, as well as chiral catalytic synthesis. In this review, we summarize the asymmetric syntheses of these compounds, and focus on the transition metal-catalyzed and organocatalytic asymmetric reaction. Finally, the further research on this field is also discussed.

Contents
1 Introduction
2 Catalytic asymmetric syntheses of indenes and their derivatives
2.1 Indene
2.2 Indanone
2.3 Indane
2.4 Indanol
2.5 Other derivatives
3 Conclusion

Key words: indene, indanone, indane, indanol, stereoselectivity, asymmetric synthesis

CLC Number: 

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