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Progress in Chemistry 2016, Vol. 28 Issue (6): 917-933 DOI: 10.7536/PC151225 Previous Articles   Next Articles

• Review and comments •

Determination and Parameterization of the Heterogeneous Uptake Coefficient of Dinitrogen Pentoxide (N2O5)

Wang Haichao, Lu Keding*   

  1. State Key Joint Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 41375124,91544225,21190052,41121004), the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDB05010500), and the Special Fund of State Key Joint Laboratory of Environment Simulation and Pollution Control (No.13Z02ESPCP).
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Particulate pollution is a major air pollution problem in Chinese mega-cities. Under such conditions, the atmospheric gas-phase chemistry is strongly influenced by heterogeneous reactions, of which to quantify the heterogeneous reaction processes of N2O5 is essential for the understanding of the nighttime oxidation capacity, regional NOx budget, photochemical ozone prodution, etc. In this paper, we extensively review the research progress of the N2O5 heterogeneous reaction processes such as its reaction mechanism, measurement techniques of the corresponding uptake coefficient (γN2O5) and the measurement results on different aerosol substrates. The heterogeneous reaction processes of N2O5 is a typical reactive uptake process which can be ideally studied by the aerosol flow tube system. The corresponding laboratory kinetic studies are started from model aerosols (sulfate), and evolved to be more realistic aerosols according to the accumulated knowledges on the aerosol properties obtained in field studies. It is found that the γN2O5 varied from 0.001 to 0.2 on different aerosol substrates, more than two orders of magnitude. The variation is influenced by the ambient temperature, relative humidity, mixing state, phase state, aerosol chemical compositions like NO3-, Cl-, SO42-, liquid water content (LWC), organics, etc., of which the uptake coefficient is higher with higher LWC, Cl-, SO42- while lower with higher NO3- and organics. The avaiable field studies in the United States and Europe showed that, to describe γN2O5, these impact factors can't be independently expressed; and the dependence seems to be very complicated and cross correlated. Therefore the state of art parameterization methods of γN2O5 developed from lab kinetic studies are still not able to describe the field observations. Since high aerosol loading and high N2O5 are always co-located at urban aeras, more field observations and sucessful parameterization of γN2O5 is proposed to be conducted in typical urban conditions including Chinese megacity regions.

Contents
1 Introduction
2 Proposed Mechanisms of the N2O5 heterogeneous uptake
3 Measurement of the heterogeneous uptake coefficient of N2O5 in the simulated system
3.1 Measurement techniques
3.2 Measurement results on different aerosol substrates
4 Measurement of the heterogeneous uptake coefficient of N2O5 in the field
5 The parameterization of the heterogeneous uptake coefficient of N2O5
6 Conclusion and outlook

Key words: dinitrogen pentoxide (N2O5), aerosol, heterogeneous reaction, uptake coefficient, parameterization

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