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Progress in Chemistry 2016, Vol. 28 Issue (5): 647-656 DOI: 10.7536/PC151110 Previous Articles   Next Articles

• Review and comments •

Preparation and Application of Graphene/Cellulose Composites

Gao Yurong1,2, Huang Pei1, Sun Peipei1, Wu Min1*, Huang Yong1   

  1. 1. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China;
    2. University of Chinese Academy of Sciences, Beijing 100049, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No.51472253, 51172247, 51373191).
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Graphene is a one-atom-thick planar sheet of sp2-bonded carbon atoms densely packed together in a honeycomb hexagonal lattice. The exceptional structure endows graphene with excellent electrical, mechanical, thermal, and optical properties. Up to now, considerable efforts have been made to explore its application in varied areas, such as catalyst, battery, sensor and etc. Cellulose, one of the most abundant natural polymer on earth, is featured by non-toxicity, renewability, biodegradability and biocompatibility. The hydrophilicity and hydrophobicity, originated from the enriched O-H and C-H, respectively, have made cellulose an ideal candidate for the fabrication of graphene-based materials. So far, graphene/cellulose composites have shown great potential in the applications of transparent conductive flexible films, supercapacitors, drug delivery, UV-protection, sensors, absorbents and so on. In this review, we study the interaction between cellulose materials and graphene materials. Subsequently, the mixing technics, fabrication methods, and application of the graphene/cellulose composites are summarized. Finally, problems, such as dispersion of graphene in cellulose and production efficiency, hampering its up-scale application, have been pointed out.

Contents
1 Introduction
2 Interactions between graphene and cellulose
3 Mixing methods of graphene/cellulose composite
3.1 Solution mixing
3.2 Melting mixing
3.3 Others
4 Processing of graphene/cellulose composite
4.1 Regeneration of cellulose gel
4.2 Vacuum filtration
4.3 Solution coating
4.4 Dip and dry
4.5 Film transfer
4.6 Aerogel through freeze drying
5 Applications of graphene/cellulose composite
5.1 Thin film materials
5.2 Supercapacitors
5.3 Drug delivery
5.4 UV-protection
5.5 Sensors
5.6 Absorbents
5.7 Others
6 Conclusion

Key words: cellulose, graphene, graphene oxide, composite

CLC Number: 

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