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Progress in Chemistry 2016, Vol. 28 Issue (4): 482-496 DOI: 10.7536/PC150941 Previous Articles   Next Articles

• Review and comments •

The Advance of Imidazoledicarboxylate Derivatives-Based Coordination Polymers

Jia Yingying, Li Yang, Zhou Ruisha, Song Jiangfeng*   

  1. Department of Chemistry, North University of China, Taiyuan 030051, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Young Scholars Foundation of China(No.21201155), the Natural Science Young Scholars Foundation of Shanxi Province(No. 2012021007-5, 2013021008-6), the Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi, and the 131 Talent Plan of Higher Learning Institutions of Shanxi.
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Imidazoledicarboxylate and its 2-position substituted derivatives as a kind of organic ligands with multiple coordination sites, strong coordination abilities and outstanding features of various coordination fashions have been extensively studied and applied in coordination chemistry. Up to now, hundreds of coordination complexes based on imidazoledicarboxylate and its 2-position substituted derivatives with novel topology structures as well as potential applications in numerous areas, have been reported by domestic and foreign researchers. The coordination modes are summarized in the review. The coordinate features, the types of imidazoledicarboxylate derivatives as well as the related coordination polymers, which are classified into two groups according to the different imidazoledicarboxylate 2-position substituted derivatives with alkyl and bulky aromatic groups. Moreover, the synthesis, crystal structures, potential applications such as fluorescence, gas adsorption, magnetic, catalytic and dielectric properties of corresponding polymers are also simply described. Finally, the research prospects of coordination polymers based on imidazoledicarboxylate derivatives are proposed.

Contents
1 Introduction
2 The features of imidazoledicarboxylate coordination
3 The research progress of complexes based on imidazoledicarboxylate
4 The research progress of complexes based on imidazoledicarboxylate derivatives
4.1 Imidazoledicarboxylate derivatives with alkyl groups
4.2 Imidazoledicarboxylate derivatives with aromatic groups
5 Properties
5.1 Fluorescence
5.2 Gas adsorption
5.3 Magnetism
5.4 Catalysis
5.5 Dielectric
6 Outlook

Key words: imidazoledicarboxylate, coordination polymers, coordination mode, properties

CLC Number: 

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