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Progress in Chemistry 2016, Vol. 28 Issue (2/3): 193-203 DOI: 10.7536/PC150935 Previous Articles   Next Articles

• Review and comments •

Phosphorus-Based Composite Anode Materials for Secondary Batteries

Li Jiaoyang, Wang Li*, He Xiangming*   

  1. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Key Basic Research Program of China (973) (No. 2013CB934000)and Beijing High School Young Talents Plan (YETP0157).
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Secondary batteries play important roles in energy storage. Secondary batteries such as lithium/sodium-ion batteries are promising for portable electronic devices, electric vehicles and green energy storage. The research on novel electrode materials is important for rechargeable battery of next generation. Phosphorus is attractive as anode materials due to its high theoretical specific capacity and abundant resources. However, there are many unknown aspects of phosphorus materials, which hinders its development and application, especially in the field of energy storage. This paper focuses on the properties of all the allotropes of phosphorus, and briefly introduces the research advances of phosphorus anode in recent years, including preparation, the effects of matrix structure on electrochemical performances and on the mechanisms. Meanwhile, the paper prospects the development trend of phosphorus based composites, aiming at further application in secondary batteries.

Contents
1 Introduction
2 The properties of all the allotropes of phosphorus
3 The research advances of phosphorus anode materials
4 The effect of matrix structure
4.1 Porous carbon
4.2 Nanotube
4.3 Graphene
5 Conclusion

Key words: phosphorus materials, secondary battery, anode, matrix structure, electrochemical performances

CLC Number: 

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