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Progress in Chemistry 2016, Vol. 28 Issue (2/3): 363-374 DOI: 10.7536/PC150820 Previous Articles   Next Articles

• Review and comments •

Advances in DMF and C5/C6 Alkanes Production from Lignocellulose

Yang Yue1,2, Liu Qiying1, Cai Chiliu1,3, Tan Jin1, Wang Tiejun1, Ma Longlong1,2*   

  1. 1. key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;
    2. Department of Chemistry, University of Science and Technology of China, Hefei 230026, China;
    3. University of Chinese Academy of Sciences, Beijing 100049, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No.51576199), the National Basic Research Program of China (973 Program) (No.2012CB215304),and the Science and Technology Plan Key Project in Guangdong Province of China (No.2014A010106019).
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Lignocellulosic biomass is an important renewable resource, and has potential application in high quality biofuels to substitute fossil energy and reduce green house gas emission. Among those high quality biofuels, oxygen-contained 2,5-dimethyl furan (DMF) and C5/C6 alkanes show particular interests because these two kinds fuels could be produced from biomass via 5-hydroxymethyl furfural (HMF) intermediate. DMF is an ideal replacement and/or dopant for the presently used gasoline by enhancing combustion efficiency and reducing contaminant emission because of its higher energy density, higher octane number and higher boiling point. On the other hand, C5/C6 alkanes are the important gasoline components for adjusting the octane number and volatile properties. In this paper, combining our studies, we systematically summarize the status-of-the-art technologies for HMF synthesis from cellulose, and DMF and C5/C6 alkanes production by selective and complete hydrodeoxygenation of HMF respectively, depended on reaction medium, catalyst and pathway. The reaction mediums include water, ionic liquid, polar aprotic organic solvent and water contained biphasic solvent; and catalysts include inorganic acid, metal salt, solid acid and supported catalyst. Finally, the future of biomass derived DMF and C5/C6 alkanes production is remarked and prospected.

Contents
1 Introduction
2 HMF from cellulose
2.1 Mechanism
2.2 Reaction medium
2.3 Catalysic system
2.4 Side reaction
3 DMF from HMF through selective hydrogenolysis
3.1 Mechanism
3.2 Reaction medium
3.3 Catalysic system
4 C5/C6 alkanes from cellulose
4.1 Pathway of alkanes
4.2 Catalysic system
5 Conclusion and outlook

Key words: cellulose, DMF, HMF, C5/C6 alkane, catalyst, reaction mechanism

CLC Number: 

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