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Progress in Chemistry 2015, Vol. 27 Issue (12): 1722-1731 DOI: 10.7536/PC150642 Previous Articles   Next Articles

• Review and comments •

Investigation of Technology for Lithium-Oxygen Battery

Cai Kedi1,2*, Zhao Xue1, Tong Yujin2, Xiao Yao1, Gao Yong3, Wang Cheng3   

  1. 1. Liaoning Engineering Technology Research Center of Supercapacitor, Bohai University, Jinzhou 121013, China;
    2. Interfacial Molecular Spectroscopy Group, Fritz-Haber-Institut of the Max Planck Society, Berlin 14195, Germany;
    3. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No. 21206083,21373002).
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Lithium-oxygen battery is a metal-air battery using lithium as the negative electrode, oxygen in the air as the positive electrode reactant. Because it has high theoretical specific energy and environmentally friendly advantages, the lithium-oxygen battery has been studied in recent years. In this work, it shows the latest research progress of key technology for lithium-oxygen battery, including positive electrode materials, catalysts, electrolyte, negative electrode and structure of battery. And on this basis, we outlook its future development, providing new ideas and methods for the research of other metal-air battery.

Contents
1 Introduction
2 Working principle of lithium-oxygen battery
3 Positive electrode
3.1 Carbon material
3.2 Composite material
3.3 Non-carbon material
3.4 Coating
4 Catalyst of positive electrode
5 Electrolyte
6 Negative electrode
7 Conclusion and outlook

Key words: lithium-oxygen battery, positive electrode material, catalyst, electrolyte, negative electrode

CLC Number: 

[1] Zhang T, Zhou H S. Angew. Chem. Int. Ed., 2012, 124(44): 11224.
[2] Suntivich J, Gasteiger H A, Yabuuchi N, Nakanishi H, Goodenough J B, Yang S H. Nat. Chem., 2011, 3: 546.
[3] Abraham K M, Jiang Z J. Electrochem. Soc.,1996,143(1): 1.
[4] Ogasawara T, Debart A, Holzapfel M, Bruce P G. J. Am. Chem. Soc., 2006, 128: 1390.
[5] Debart A, Paterson A J, Bao J L, Bruce P G. Angew. Chem. Int. Ed., 2008, 47: 4521.
[6] 张栋(Zhang D), 张存中(Zhang C Z), 穆道斌(Mu D B), 吴伯荣(Wu B R), 吴锋(Wu F).化学进展(Progress in Chemistry), 2012, 24(12): 2472.
[7] Gao Y, Wang C, Pu W H, Liu Z X, Deng C S, Zhang P, Mao Z Q. Int. J.Hydrogen Energy, 2012, 37(17): 12725.
[8] Xu J J, Xu D, Wang Z L, Wang H G, Zhang L L, Zhang X B. Angew. Chem. Int. Ed., 2013, 52(14): 3887.
[9] Zhang L L, Zhang X B, Wang Z L, Xu J J, Xu D, Wang L M. Chem.Commun., 2012, 48(61): 7598.
[10] Cai K D, Pu W H, Gao Y, Hou J B, Deng C S, Wang C, Mao Z Q. Int. J. Hydrogen Energy, 2013, 38(25): 11023.
[11] Cai K D, Jiang H J, Pu W H. Int. J. Electrochem. Soc., 2014, 9(1): 390.
[12] Lu Y, Gasteiger H A, Crumlin E,Jr R M,Shao-Horn Y. J. Electrochem. Soc., 2010, 159(9): A1016.
[13] Bryantsev V S, Blanco M, Faglioni F. J. Phys. Chem. A, 2010, 114(31): 8165.
[14] Christensen J, Albertus P, Sanchez-Carrera R S, Lohmann T, Kozinsky B, Liedtke R, Ahmed J, Kojic A. J. Electrochem. Soc., 2012, 159 (2): R1.
[15] Viswanathan V, Thygesen K S, Hummelshoj J S, Norskov J K, Girishkumar G, McCloskey B D, Luntz A C. J. Chem. Phys., 2011, 135 (21): 214704.
[16] Tran C, Yang X, Qu D. J. Power Sources, 2010, 195(7): 2057.
[17] Xiao, J, Wang D H, Xu W, Wang D Y, Williford R E, Liu J, Zhang J. J. Electrochem. Soc., 2010, 157(4): A487.
[18] Li Y L, Li X F, Geng D S, Tang Y J, Li Y Y, Dodelet J P, Michel L, Sun X L. Carbon, 2013, 64: 170.
[19] Ma S B, Lee D J, Roev V, Im D M, Doo S G. J. Power Sources, 2013, 244: 494.
[20] Song Y F, Wang X Y, Bai Y S, Wang H, Hu B A, Shu H B, Yang X K, Yi L H, Ju B W, Zhang X Y. T. Nonferr. Metal. Soc., 2013, 23(12): 3685.
[21] Cui Z H, Fan W G, Guo X X. J. Power Sources, 2013, 235: 251.
[22] Nie H J, Zhang Y N, Zhou W, Li J, Wu B S, Liu T, Zhang H M. Electrochim. Acta, 2014, 150: 205.
[23] Li J, Zhang Y N, Zhou W, Nie H J, Zhang H M. J. Power Sources, 2014, 262: 29.
[24] Cui Z H, Guo X X. J. Power Sources, 2014, 267: 20.
[25] Lin X J, Lu X, Huang T, Liu Z L, Yu A S. J. Power Sources, 2013, 242: 855.
[26] Lei Y, Lu J, Luo X Y, Wu T P, Du P, Zhang X Y, Ren Y, Wen J G, Miller D J, Miller J T, Sun Y K, Elam J W, Amine K. Nano Lett., 2013, 13(9): 4182.
[27] Riaz A, Jung K N, Chang W Y, Shin K H, Lee J W. ACS Appl. Mater.Interfaces, 2014, 6(20): 17815.
[28] Lee H, Kim Y J, Lee D J, Song J C, Lee Y M, Lim H T, Park J K. J. Mater. Chem. A, 2014, 2(30): 11891.
[29] Oh D Y, Qi J F, Han B H, Zhang G R, Garney T J, Ohmura J, Zhang Y, Yang S H, Belcher A M. Nano Lett., 2014, 14(8): 4837.
[30] Lin X J, Shang Y S, Huang T, Yu A S. Nanoscale, 2014, 6(15): 9043.
[31] Hung T F, Mohamed S G, Shen C C, Tsai Y Q, Chang W S, Liu R S. Nanoscale, 2013, 5(24): 12115.
[32] Shui J L, Wang H H, Liu D J. Electrochem. Commun., 2013, 34: 45.
[33] Riaz A, Jung K N, Chang W, Lee S B, Lim T H, Park S J, Song R H, Yoon S, Shin K H, Lee J W. Chem.Commun., 2013, 49(53): 5984.
[34] Wei Z H, Tan P, An L, Zhao T S. Appl. Energy, 2014, 130: 134.
[35] Cho S M, Lee J K, Yoon W Y. Electrochim. Acta, 2015. 158: 246.
[36] Zahoor A, Jang H S, Jeong J S, Christy M, Hwang Y J, Nahm K S. RSC Adv., 2014, 4(18): 8973.
[37] Zeng J, Francia C, Amici J, Bodoardo S, Penazzi N. J. Power Sources, 2014, 272: 1003.
[38] Bhattacharya P, Nasybulin E N, Engelhard M H, Kovarik L, Bowden M E, Li X S, Gaspar D J, Xu W, Zhang J G. Adv. Funct. Mater., 2014, 24(47): 7510.
[39] Li P F, Zhang J K, Yu Q L, Qiao J S, Wang Z H, Rooney D, Sun W, Sun K N. Electrochim. Acta, 2015, 165: 78.
[40] Yu L, Shen Y, Huang Y H. J.Alloys Compd., 2014, 595: 185.
[41] Cao Y, Cai S R, Fan S C, Hu W Q, Zheng M S, Dong Q F. Faraday Discuss., 2014, 172: 215.
[42] Jung K N, Riaz A, Lee S B, Lim T H, Park S J, Song R H, Yoon S, Shin K H, Lee J W. J. Power Sources, 2013, 244: 328.
[43] Lim S H, Kim D H, Byun J Y, Kim B K, Yoon W Y. Electrochim. Acta, 2013, 107: 681.
[44] Huang Z, Zhang M, Cheng J F, Gong Y P, Li X, Chi B, Pu J, Jian L. J. Alloys Compd., 2015, 626: 173.
[45] Ko B K, Kim M K, Kim S H, Lee M A, Shim S E, Baeck S H. J.Mol.Catal A:Chem., 2013, 379: 9.
[46] 黄洋(Huang Y), 罗仲宽(Luo Z K), 王芳(Wang F), 吴其兴(Wu Q X), 徐扬海(Xu Y H), 陈静(Chen J), 李豪君(Li H J).材料导报A(Materials Review),2015, 29(3): 8.
[47] Zheng H, Xiao D D, Li X, Liu Y L, Wu Y, Wang J P, Jiang K, Chen C, Gu L, Wei X L, Hu Y S, Chen Q, Li H. Nano Lett., 2014, 14(8): 4245.
[48] Visco S J, Nimon V Y, Petrov A, Pridatko K, Goncharenko N, Nimon E, Jonghe L D, Volfkovich Y M, Bograchev D A. J. Solid State Electrochem., 2014, 18(5): 1443.
[49] Zhang J Q, Sun B, Xie X Q, Kretschmer K, Wang G X. Electrochim. Acta, 2015. 36: 151.
[50] Lu Q, Gao Y G, Zhao Q, Li J, Wang X H, Wang F S. J. Power Sources, 2013, 242: 677.
[51] Cai K D, Pu W H, Gao Y, Hou J B, Deng C S, Wang C, Mao Z Q. Int. J. Hydrogen Energy, 2013, 38(25): 11023.
[52] Jung K N, Lee J I, Jung J H, Shin K H, Lee J W. Chem.Commun., 2014, 50(41): 5458.
[53] Lee D J, Lee H, Song J C, Ryou M H, Lee Y M, Kim H T, Park J K. Electrochem. Commun., 2014, 40: 45.
[54] Le H T, Kalubarme R S, Ngo D T, Jang S Y, Jung K N, Shin K H, Park C J. J. Power Sources, 2015, 274: 1188.
[55] Girishkumar G, McCloskey B, Luntz A C, Swanson S, Wilcke W. J. Phys. Chem. Lett., 2010, 1(14): 2193.
[56] Armand M, Tarascon J M. Nature, 2008, 451: 652.
[57] Zhang J, Xu W, Liu W. J. Power Sources, 2010, 195(21): 7438.
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