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Progress in Chemistry 2015, Vol. 27 Issue (9): 1167-1181 DOI: 10.7536/PC150210 Previous Articles   Next Articles

• Review and comments •

Light Metal Complex Hydride Hydrogen Storage Systems

Liu Xin1, Wu Chuan1,2, Wu Feng1,2, Bai Ying1,2*   

  1. 1. Beijing Key Laboratory of Environment Science and Engineering, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;
    2. National Development Center of High Technology Green Materials, Beijing 100081, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21476027), the Research Fund for the Doctoral Program of Higher Education of China (No. 20121101110042), and the Program for New Century Excellent Talents in University (No. NCET-13-0033).
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The key technology for hydrogen energy effectively is to develop safe, economical and efficient hydrogen storage system. Among all the hydrogen storage technologies at present, solid-state hydrogen storage material has got a lot of attentions because of its outstanding advantages including high density, excellent cycle property, safe and convenient storage mode. Complex hydride material has the highest hydrogen storage density; and light metal complex hydride hydrogen storage systems (LMCHHSS) which have high hydrogen storage density and excellent hydrogen storage property are the research emphasis with good achievements. The decomposition mechanisms, thermodynamic and kinetic properties, cycling performances, crystal structures, research status of LMCHHSS, including borohydride system, alanate system and amide system, are discussed in the paper. At last, some promising research directions to reduce thermodynamic stability, improve kinetic property and cycling hydrogen storage property, such as binary or multicomponent composite system, efficient catalyst nanoparticle, superior reaction environment, or the comprehensive synergistic effect of the above, are suggested for the developing trends of the domain in the future.

Contents
1 Introduction
2 Light metal borohydride hydrogen storage system
2.1 LiBH4 hydrogen storage system
2.2 NaBH4 hydrogen storage system
2.3 KBH4 hydrogen storage system
2.4 Mg(BH4)2 hydrogen storage system
3 Light metal alanate hydrogen storage system
3.1 LiAlH4 hydrogen storage system
3.2 NaAlH4 hydrogen storage system
3.3 Mg(AlH4)2 hydrogen storage system
4 Alkali metalamide hydrogen storage system
4.1 LiNH2 hydrogen storage system
4.2 NaNH2 hydrogen storage system
5 Conclusion and outlook

Key words: light metal complex hydride, hydrogen storage system, reaction mechanism, thermodynamic property, kinetic property

CLC Number: 

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