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Progress in Chemistry 2015, Vol. 27 Issue (9): 1182-1190 DOI: 10.7536/PC150165 Previous Articles   Next Articles

• Review and comments •

Platinum Complexes Catalyzed Hydrosilylation of Trichlorosilane and Allyl Chloride

Shao Yuegang1,2, Liu Ji2*, Chen Xiangqian2, Jin Peiyu2, Tang Hongding1*   

  1. 1. College of Chemistry and Molecule Sciences, Wuhan University, Wuhan 43007;
    2. Zhejiang Wynca Chemical Industrial Group Co., Ltd., Jiande 311600, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the China Postdoctoral Science Foundation (No.2015M571900).
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As an important intermediate for the production of silane coupling agent, γ-chloropropyl trichlorosilane is mainly obtained by Pt catalyzed hydrosilylation of allyl chloride and trichlorosilane. The industrial scale of γ-chloropropyl trichlorosilane has already exceeded 10000 tons. Despite great success achieved in this field, the hydrosilylation reaction is often accompanied with the low selectivity and high amounts of byproducts. Much progress in this hydrosilylation reaction has been made through the modulation of ligands on platinum complexes and their immobilization during the past decades. This paper reviews the progress in platinum complexes used as catalysts in the hydrosilylation reaction of trichlorosilane and allyl chloride,particularly focus on the impacts of ligands to soluble homogeneous platinum complex catalysts and supported platinum complex catalysts. Meanwhile, the progress in its reaction mechanism is presented. At last, some ideas are provided for future research.

Contents
1 Introduction
2 Homogeneous platinum complexes catalysts
2.1 Speier catalysts
2.2 Karstedt catalysts
2.3 Other homogeneous platinum complexes catalysts
3 Supported platinum complexes catalysts
3.1 Inorganic materials supported platinum complexes catalysts
3.2 Soluble polymer supported platinum complexes catalysts
3.3 Ionic liquids supported platinum complexes catalysts
4 Mechanism study
5 Conclusion

Key words: γ-chloropropyl trichlorosilane, hydrosilylation, platinum complexes, mechanism

CLC Number: 

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