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Progress in Chemistry 2015, Vol. 27 Issue (9): 1230-1239 DOI: 10.7536/PC150138 Previous Articles   Next Articles

• Review and comments •

Ionics Fluorescent Chemsensor Based on Pyrene

Zhong Keli1, Guo Baofeng1, Zhou Xue1, Cai Kedi1, Tang Lijun1*, Jin Longyi2*   

  1. 1. College of Chemistry, Chemical Engineering and Food Safety, Bohai University, Food Safety Key Lab of Liaoning Province, Jinzhou 121013, China;
    2. Key Laboratory for Organism Resources of the Changbai Mountain and Functional Molecules, Ministry of Education, Department of Chemistry, College of Science, Yanbian University, Yanji 133002, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work is supported by the National Natural Science Foundation of China (No.21304009,21476029,21176029,21164013), the Program for Liaoning Excellent Talents in University (No.LJQ2014125,LR2015001), the National Key Technologies R&D Program of China during the 12th Five-Year Plan Period(No. 2012BAD29B06), and the Food Safety Key Laboratory of Liaoning Province (No. LNSAKF2011025).
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Pyrene is a simple aromatic molecule, and it can easily form dynamic and static excimer in solution, which shows long wavelength fluorescence emission. Owing to the different fluorescence emission wavelengths of pyrene monomer and excimer, pyrene is often used as fluorophore for the synthesis of various fluorescent sensors. The progress of pyrene-based fluorescent chemosensors, including the molecular design, mechanism and their application to single-cation, dication as well as anion recognition are summarized. The developing prospect of this type of fluorescent chemosensor is envisaged in this review.

Contents
1 Introduction
2 Fluorescence sensors for single-cation
2.1 Fluorescent sensors for Hg2+ 2.2 Fluorescent sensors for Cu2+ 2.3 Fluorescent sensors for Zn2+ 2.4 Fluorescent sensors for Ag+ 2.5 Fluorescent sensors for other single-cation 3 Fluorescence sensors for dication
3.1 Fluorescent sensors for Hg2+,Cu2+ 3.2 Fluorescent sensors for Hg2+,Pb2+ 3.3 Fluorescent sensors for other dication
4 Fluorescent sensors for anion
5 Conclusion

Key words: pyrene, fluorescent sensors, cation, anion

CLC Number: 

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