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Progress in Chemistry 2015, Vol. 27 Issue (5): 503-510 DOI: 10.7536/PC150112 Previous Articles   Next Articles

• Review and evaluation •

Green Routes for Synthesis of Zeolites

Li Yang1, Sun Hongman1,2, Wang Youhe*1,2, Xu Benjing1, Yan Zifeng*1   

  1. 1. State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, CNPC, China University of Petroleum, Qingdao 266580, China;
    2. School of Science, China University of Petroleum(East China), Qingdao 266580, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the Petrochemical Joint Funds of NSFC-CNPC (No. U1362202) and Postgraduate Innovation Project of China University of Petroleum (East China) (No. YCX2014037).
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Zeolites have been widely used as adsorbents, heterogeneous catalysts and ion-exchange materials due to their unique pore structure, strong acidity and high hydrothermal stability. At present, most of zeolites are synthesized by hydrothermal method, involving the use of commercial silicon- and aluminum-containing reagents and organic templates, which leads to high cost, low efficiency and seriously environmental pollution. Therefore, the research of highly efficient and green routes for synthesis of zeolites is of great significance. Three aspects including the greenization of the raw materials, synthesis conditions and synthesis methods are reviewed in this paper. The existing problems and future direction of development are also put forward.

Contents
1 Introduction
2 The greenization of raw materials
2.1 Synthesis of zeolite from kaolin
2.2 Synthesis of zeolite from diatomite
3 The greenization of synthesis conditions
3.1 Directed method
3.2 Seed solution-assisted method
3.3 Crystal seed-directed method
4 The greenization of synthesis methods
5 Conclusion

Key words: zeolite, natural mineral, organotemplate-free, solvent-free, green routes

CLC Number: 

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Abstract

Green Routes for Synthesis of Zeolites