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Progress in Chemistry 2015, Vol. 27 Issue (5): 511-521 DOI: 10.7536/PC141137 Previous Articles   Next Articles

• Review and evaluation •

TM2+:Ⅱ-Ⅵ Mid-Infrared Materials

Chen Yuanzhi1,2, Zhang Le*1,2, Huang Cunxin3, Zhang Jian*1,2, Tang Dingyuan1,2, Shen Deyuan1,2   

  1. 1. School of Physics Electronic Engineering, Jiangsu Normal University, Xuzhou 221116, China;
    2. Jiangsu Key Laboratory of Advanced Laser Materials and Devices, Jiangsu Normal University, Xuzhou 221116, China;
    3. Beijing Sinoma Synthetic Crystal Co. Ltd., Beijing 100018, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 51402133, 51302115, 61405081) and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).
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TM2+ :Ⅱ-Ⅵ compounds have become the most potential materials used for infrared laser due to the advantage of wide tunable range, small excited state absorption, high absorption and emission cross section and high quantum efficiency at room temperature. The research progress of TM2+:Ⅱ-Ⅵ laser materials are retrospect in this paper. Both the applications of TM2+:Ⅱ-Ⅵ materials in laser devices and their preparation methods are reviewed, respectively. The laser performance of typical TM2+:Ⅱ-Ⅵ mid-infrared materials are summarized in detail, and the preparation methods for monocrystalline and polycrystalline of these materials are listed systematically. At last, the existing problems in this field are pointed out, and the development prospects and research trends are prospected.

Contents
1 Introduction
2 The structure and species of TM2+:Ⅱ-Ⅵ compounds
3 The laser properties of TM2+:Ⅱ-Ⅵ materials
3.1 Cr2+:ZnSe
3.2 Cr2+:ZnS
3.3 Fe2+:Ⅱ-Ⅵ materials
4 Preparation method of TM2+:Ⅱ-Ⅵ material
4.1 Preparation method of TM2+:Ⅱ-Ⅵ single crystal
4.2 Preparation method of TM2+:Ⅱ-Ⅵ poly-crystalline and ceramic materials
5 Conclusion

CLC Number: 

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Abstract

TM2+:Ⅱ-Ⅵ Mid-Infrared Materials