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Progress in Chemistry 2015, Vol. 27 Issue (5): 539-549 DOI: 10.7536/PC141120 Previous Articles   Next Articles

• Review and evaluation •

Synthesis and Applications of ATRP Macromolecular Initiator

Mu Siyang, Guo Jing*, Yu Chunfang, Gong Yumei, Zhang Sen   

  1. School of Textile & Material Engineering, Dalian Polytechnic University, Dalian 116034, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 51373027).
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Atom transfer radical polymerization (ATRP), as a new type of controllable/living polymerization reaction, has been applied in many fields widely, such as the structure design of the polymer,the surface modification of inorganic materials, protein detection, biopolymer separation, antibacterial and antifouling, etc. Three major factors are involved in the reaction process:monomer, initiator system (initiator, catalyst, complexant), and reaction medium, the core element of which is the choice of ATRP initiator. The microstructure and performance of the initiator are the key factors for the ATRP reaction. In this paper, we firstly introduce the types and properties of the micromolecule initiator and the reaction mechanism of the ATRP briefly. Then,we emphatically summarize the latest advances about the preparation methods of the ATRP macromolecular initiator in recent years, such as functional group reaction, coupling reaction and free radical polymerization. Moreover, we also review the latest application of the macromolecular initiator through ATRP reaction in the structure design of the polymer, the surface modification of inorganic materials and biological materials. Finally, an outlook for the prospective development of the ATRP initiator system is given.

Contents
1 Introduction
2 Small molecular initiator
3 Preparation of the macromolecular initiator
3.1 Functional group reaction method
3.2 Coupling reaction method
3.3 Free radical polymerization method
4 Application
4.1 Structure design of the polymer
4.2 Surface modification of inorganic materials
4.3 Surface modification of biomolecular
5 Conclusion

Key words: atom transfer radical polymerization (ATRP), macromolecular initiator, molecular design, surface modification

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