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Progress in Chemistry 2015, Vol. 27 Issue (4): 404-415 DOI: 10.7536/PC141024 Previous Articles   Next Articles

• Review and evaluation •

Graphene/Metal Oxide Composites as Electrode Material for Supercapacitors

Li Dan1, Liu Yurong1,2, Lin Baoping*1, Sun Ying1, Yang Hong1, Zhang Xueqin1   

  1. 1. School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China;
    2. Research Institute for New Materials Technology, Chongqing University of Arts and Science, Yongchuan 402160, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21304018, 21374016).
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Supercapacitor has been recognized as a very promising new energy storage device due to its high power density and long cycle life. Carbon materials, metal oxides and conductive polymers are three more commonly utilized electrode materials for supercapacitors. The combination of the cycling stability of graphene and high capacity of metal oxide provides the graphene/metal oxide composite superiors performance. Consequently, significant research interest has been directed into the research of the graphene/metal oxide composite. In this paper, we present a review on the research progress of the graphene/metal oxide composite for supercapacitor application in term of the types of metal oxides, grapheme structure and preparation methods. Furthermore, the optimum synthesizing conditions and an outlook of the developing trend for the graphene/metal oxide composite are summarized.

Contents
1 Introduction
2 MnO2/graphene composites
2.1 Solvothermal (hydrothermal) method
2.2 Electrochemical deposition
2.3 Chemical reaction
2.4 Self-assembly method
3 RuO2/graphene composites
3.1 Sol-gel method
3.2 Solvothermal (hydrothermal) method
4 NiO/graphene composites
4.1 Chemical precipitation
4.2 Solvothermal (hydrothermal) method
4.3 Other methods
5 Co3O4/graphene composites
5.1 Chemical precipitation
5.2 Solvothermal (hydrothermal) method
5.3 Other methods
6 ZnO/graphene composites
7 Other metal oxides
8 Binary metal oxides
9 Conclusion

Key words: supercapacitor, graphene, metal oxide, composites, preparation methods, electrochemical performance

CLC Number: 

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